Atomic substructure engineering provides new opportunities for the designing newly and efficient catalysts with diverse atom ensembles, trimmed electron bands, and way-out coordination environments, creating unique contributing to concertedly catalyze water oxidation, which is of great significance for proton exchange membrane water electrolysis (PEMWE). Herein, nest-scheme RuIrLa nanocrystals with dense coherent interfaces as built-in substructures are firstly fabricated by using commercial ZnO particles as acid-removable templates, through a La-stabilized coherent epitaxial growth of nanoparticles (NPs). The obtained nests exhibit a low overpotential of 198 mV at 10 mA cm, and the RuIrLa||Pt/C module equipped in PEMWE operates stably at a cell voltage potential of 1.
View Article and Find Full Text PDFRare earth microalloying nanocrystals have gotten widespread attention due to their unprecedented performances with customization-defected nanostructures, divided energy bands, and ensembled surface chemistry, regarded as a class of ideal electrocatalysts for oxygen evolution reaction (OER). Herein, a lanthanide microalloying strategy is proposed to fabricate strain wave-featured LaRuIr nanocrystals with oxide skin through a rapid crystal nucleation, using thermally assisted sodium borohydride reduction in aqueous solution at 60 °C. The atomic strain waves with alternating compressive and tensile strains, resulting from La-stabilized edge dislocations in form of Cottrell atmospheres.
View Article and Find Full Text PDFIn an investigation of diseases from plant-parasitizing nematodes in Henan Province, a cyst nematode was found on tobacco roots and in rhizosphere soil. We identified this strain as a new cyst nematode subspecies, sbsp.n.
View Article and Find Full Text PDFMetal-doped ruthenium oxides with low prices have gained widespread attention due to their editable compositions, distorted structures, and diverse morphologies for electrocatalysis. However, the mainstream challenge lies in breaking the so-called seesaw relationship between activity and stability during acidic oxygen evolution reaction (OER). Herein, strain wave-featured Mn-RuO nanowires (NWs) with asymmetric Ru-O-Mn bonds are first fabricated by thermally driven rapid solid phase conversion from RuMn alloy nanoparticles (NPs) at moderate temperature (450 °C).
View Article and Find Full Text PDFMaize is the largest crop planted in China. Nine species of cyst nematodes have been reported to affect maize production. Heterodera zeae, H.
View Article and Find Full Text PDFMany G protein-coupled receptors and other signaling proteins localize to the ciliary membrane for regulating diverse cellular processes. The BBSome composed of multiple Bardet-Biedl syndrome (BBS) proteins is an intraflagellar transport (IFT) cargo adaptor essential for sorting signaling proteins in and/or out of cilia via IFT. Leucine zipper transcription factor-like 1 (LZTFL1) protein mediates ciliary signaling by controlling BBSome ciliary content, reflecting how LZTFL1 mutations could cause BBS.
View Article and Find Full Text PDFCurr Drug Targets
September 2017
Estrogens play a crucial role in the growth, development, and homeostasis of various target tissues, their biological effects being mediated by the estrogen receptor (ER). In order to get a better understanding of the structural features of the modulators associated with the binding to ER, this paper provides an overview of the Quantitative Structure-Activity (QSAR) studies performed so far for estimating or predicting the activity of different ligands towards its two known subtypes (ERα and ERβ). Recent progresses in the application of these modeling studies are additionally pointed out.
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