Commercial glassy carbon plates being used as absolute intensity calibration standards in small-angle X-ray scattering applications (NIST SRM 3600) have been characterized in several recent publications. This contribution adds to the characterization by measuring the hydrogen content of a plate to be (4.8 ± 0.
View Article and Find Full Text PDFIt has been shown that single-particle wave functions, of both photons and electrons, can be created with a phase vortex, i.e., an intrinsic orbital angular momentum (OAM).
View Article and Find Full Text PDFRapid reorientational motions of the B(12)H(12)(2-) icosahedral anion, a key intermediate in borohydride dehydrogenation, are revealed by quasielastic neutron scattering (QENS) measurements of Cs(2)B(12)H(12) between 430 and 530 K. At 430 K, over the range of momentum transfers collected, the elastic incoherent structure factor (EISF) is consistent with a model for reorientational jumps about a single molecular axis. At temperatures of 480 K and higher, however, the EISF suggests the emergence of multiaxis reorientation by dynamically similar, independent jumps about two axes, on average, preserving crystallographic order.
View Article and Find Full Text PDF