Size-Pore-Dependent Methanol Sequestration from Water-Methanol Mixtures by an Embedded Graphene Slit.

The separation of liquid mixture components is relevant to many applications-ranging from water purification to biofuel production-and is a growing concern related to the UN Sustainable Development Goals (SDGs), such as "Clean water and Sanitation" and "Affordable and clean energy". One promising technique is using graphene slit-pores as filters, or sponges, because the confinement potentially affects the properties of the mixture components in different ways, favoring their separation. However, no systematic study has shown how the size of a pore changes the thermodynamics of the surrounding mixture.