Plasma Catalysis Modeling: How Ideal Is Atomic Hydrogen for Eley-Rideal?

Plasma catalysis is an emerging technology, but a lot of questions about the underlying surface mechanisms remain unanswered. One of these questions is how important Eley-Rideal (ER) reactions are, next to Langmuir-Hinshelwood reactions. Most plasma catalysis kinetic models predict ER reactions to be important and sometimes even vital for the surface chemistry.

Improving Molecule-Metal Surface Reaction Networks Using the Meta-Generalized Gradient Approximation: CO Hydrogenation.

Density functional theory is widely used to gain insights into molecule-metal surface reaction networks, which is important for a better understanding of catalysis. However, it is well-known that generalized gradient approximation (GGA) density functionals (DFs), most often used for the study of reaction networks, struggle to correctly describe both gas-phase molecules and metal surfaces. Also, GGA DFs typically underestimate reaction barriers due to an underestimation of the self-interaction energy.