Evidence of high bioaccessibility of gadolinium-contrast agents in natural waters after human oral uptake.

Considering the large occurrence of anthropogenic Gd concentrations in natural waters, its continuous usage increase in technology developments and products and the lack of data on potential Gd human exposure due to ingestion of contaminated waters, it is urgently needed to understand how gadolinium contrast agents (Gd-CAs) reacts in the human digestive system. Here, we aimed to identify through in vitro bioaccessibility tests whether Gd-CAs can be potentially assimilated by humans after oral uptake and if there is a significant difference between contrast agents. We also roughly estimated the potential bioaccessibility of anthropogenic Gd for tap waters worldwide.

Distribution and fractionation of rare earth elements in sediments and mangrove soil profiles across an estuarine gradient.

Many hypotheses have been raised about the controls of the distribution and fractionation of the rare earth elements (REE) in coastal ecosystems. Here, REE were measured in estuarine sediments and in six mangrove soil profiles along the estuarine salinity gradient of the Jaguaripe estuary, northeastern Brazil. The aim of this study was to evaluate the fractionation, distribution, remobilization, and possible sources of these elements.

Tracking hospital effluent-derived gadolinium in Atlantic coastal waters off Brazil.

The use of gadolinium (Gd) complexes as contrast agents in magnetic resonance imaging (MRI) has resulted in point source releases of anthropogenic Gd into the environment and presents the opportunity to trace the fate of wastewater plumes. Here we collected seawater samples along the coast of Northeast Brazil to investigate the influence of two submarine sewage outfalls on the distribution of Gd and other rare earth elements (REE) in the coastal waters. The shale-normalized REEs only show a small light over heavy REE enrichment and negative Ce anomalies, likely reflecting the influence of freshwater inputs.

The environmental impacts of one of the largest tailing dam failures worldwide.

The impacts of the SAMARCO iron tailing spill along more than 650 km, between the dam and the plume of the Doce River in the Atlantic, were assessed by the determination of toxic metals. The tailing spill caused a substantial increase in suspended sediment loads (up to 33,000 mg L), in addition to large depositions of waste along the Doce basin. The highest estimated transport of dissolved metals was observed for Fe (58.

Trace and major elements distribution and transfer within a benthic system: polychaete Chaetopterus variopedatus, commensal crab Polyonyx gibbesi, worm tube, and sediments.

Samples of the polychaete Chaetopterus variopedatus, worm tubes, commensal crab Polyonyx gibbesi and sediments were collected in eight sites in Todos os Santos Bay, Brazil, in order to evaluate the potential use of the polychaetes and crabs as biomonitors and to assess the relationships and accumulation of trace and major elements in different benthic compartments. Trace and major elements were determined by ICP OES. Organic carbon, total nitrogen and sulfur were determined by CNS elemental analyser.