ERIC-PCR technique applied to monitoring and quantification of DNA damage during water disinfection process.

In this work, we propose a novel application of ERIC-PCR technique to study DNA damage after ultraviolet radiation (UV) and peracetic acid (PAA) treatment for water disinfection purpose. The efficacy of both treatments on E. coli suspension was evaluated by two approaches: through monitoring of inactivation by conventional culture technique, and by analyzing DNA damage with ERIC-PCR.

Coated mesh photocatalytic reactor for air treatment applications: comparative study of support materials.

An experimental comparative study of different meshes as support materials for photocatalytic applications in gas phase is presented. The photocatalytic oxidation of dichloromethane in air was addressed employing different coated meshes in a laboratory-scale, continuous reactor. Two fiberglass meshes and a stainless steel mesh were studied regarding the catalyst load, adherence, and catalytic activity.

Kinetic model of water disinfection using peracetic acid including synergistic effects.

The disinfection efficiencies of a commercial mixture of peracetic acid against Escherichia coli were studied in laboratory scale experiments. The joint and separate action of two disinfectant agents, hydrogen peroxide and peracetic acid, were evaluated in order to observe synergistic effects. A kinetic model for each component of the mixture and for the commercial mixture was proposed.

Arsenic sorption onto titanium dioxide, granular ferric hydroxide and activated alumina: batch and dynamic studies.

The aim of this work was to evaluate and compare the efficiencies of three different adsorbents for arsenic (As) removal from water: titanium dioxide (TiO2), granular ferric hydroxide (GFH) and activated alumina (AA). Equilibrium experiments for dissolved arsenite and arsenate were carried out through batch tests. Freundlich and Langmuir isotherm models were adopted and their parameters were estimated by non-linear regressions.

Arsenic removal from water employing a combined system: photooxidation and adsorption.

A combined system employing photochemical oxidation (UV/H2O2) and adsorption for arsenic removal from water was designed and evaluated. In this work, a bench-scale photochemical annular reactor was developed being connected alternately to a pair of adsorption columns filled with titanium dioxide (TiO2) and granular ferric hydroxide (GFH). The experiences were performed by varying the relation of As concentration (As (III)/As (V) weight ratio) at constant hydrogen peroxide concentration and incident radiation.

A novel approach to explain the inactivation mechanism of Escherichia coli employing a commercially available peracetic acid.

The chemical inactivation of Escherichia coli employing a commercial mixture of peracetic acid (PAA) was studied. For this purpose, experiments were carried out using dilutions of the unmodified mixture, and also the same mixture but altered with hydrogen peroxide (HP) previously inhibited. Also, these results were compared to those obtained before employing HP alone.

A methodology for modeling photocatalytic reactors for indoor pollution control using previously estimated kinetic parameters.

A methodology for modeling photocatalytic reactors for their application in indoor air pollution control is carried out. The methodology implies, firstly, the determination of intrinsic reaction kinetics for the removal of formaldehyde. This is achieved by means of a simple geometry, continuous reactor operating under kinetic control regime and steady state.

Arsenic (III) oxidation of water applying a combination of hydrogen peroxide and UVC radiation.

Arsenic is toxic to both plants and animals and inorganic arsenicals are proven carcinogens in humans. The oxidation of As(III) to As(v) is desirable for enhancing the immobilization of arsenic and is required for most arsenic removal technologies. The main objective of this research is to apply an Advanced Oxidation Process that combines ultraviolet radiation and hydrogen peroxide (UVC/H(2)O(2)) for oxidizing aqueous solutions of As(III).

Water disinfection with UVC radiation and H2O2. A comparative study.

A generalized kinetic model resulting from several modifications of the one originally known as the Series Event Model has been applied to describe three different disinfection processes and compare their efficiencies. The work was performed in a well-defined, versatile batch reactor employing Escherichia coli as a subrogate bacteria. The following systems were studied: (i) UVC radiation alone, (ii) hydrogen peroxide alone and (iii) UVC radiation combined with hydrogen peroxide.

Dichloroacetic acid degradation employing hydrogen peroxide and UV radiation.

The degradation reaction of dichloroacetic acid employing H(2)O(2) and UVC radiation (253.7nm) has been studied in a well mixed reactor operating inside a recycling system. It has been shown that in an aqueous solution no stable reaction intermediates are formed and, at every time during the reaction, two mols of hydrochloric acid are formed for every mol of dichloroacetic acid that is decomposed and, in the same way, there is a paired agreement between the calculated TOC concentration corresponding to the unaltered dichloroacetic acid and the experimental values measured in the solution.