Rice is an important source of nutrition and energy consumed around the world. Thus, quality inspection is crucial for protecting consumers and increasing the rice's value in the productive chain. Currently, methods for rice labeling depending on grain quality features are based on image and/or visual inspection.
View Article and Find Full Text PDFThe textile industry is an important potential source of environmental pollution due to the use of chemical products. Dyes, hydrolyzed dyes, and surfactants, among others, are chemical compounds present in wastewater of textile plant. Moreover, the anionic surfactants have toxic effects for various aquatic organisms even in low concentrations.
View Article and Find Full Text PDFThe present work proposes to detect adulteration in rice flour using mineral profiles. Eighty-seven flour samples from two rice kinds (Indica and Japonica) plus thirty adulterated flour samples were analyzed by ICP OES. After obtaining the quantitative elemental fingerprint of the samples, PCA and LDA were applied.
View Article and Find Full Text PDFA simple, fast, and efficient spark discharge-laser-induced breakdown spectroscopy (SD-LIBS) method was developed for determining rice botanic origin using predictive modeling based on support vector machine (SVM). Seventy-two samples from four rice varieties (Guri, Irga 424, Puitá, and Taim) were analyzed by SD-LIBS. Spectral lines of C, Ca, Fe, Mg, N and Na were selected as input variables for prediction model fitting.
View Article and Find Full Text PDFRice is the most consumed food worldwide, therefore its designation of origin (PDO) is very useful. Laser-induced breakdown spectroscopy (LIBS) is an interesting analytical technique for PDO certification, since it provides fast multielemental analysis requiring minimal sample treatment. In this work LIBS spectral data from rice analysis were evaluated for PDO certification of Argentine brown rice.
View Article and Find Full Text PDFTetracyclines are widely used for both the treatment and prevention of diseases in animals as well as for the promotion of rapid animal growth and weight gain. This practice may result in trace amounts of these drugs in products of animal origin, such as milk and eggs, posing serious risks to human health. The presence of tetracycline residues in foods can lead to the transmission of antibiotic-resistant pathogenic bacteria through the food chain.
View Article and Find Full Text PDFThe feasibility of the application of chemometric techniques associated with multi-element analysis for the classification of grape seeds according to their provenance vineyard soil was investigated. Grape seed samples from different localities of Mendoza province (Argentina) were evaluated. Inductively coupled plasma mass spectrometry (ICP-MS) was used for the determination of twenty-nine elements (Ag, As, Ce, Co, Cs, Cu, Eu, Fe, Ga, Gd, La, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Rb, Sm, Te, Ti, Tl, Tm, U, V, Y, Zn and Zr).
View Article and Find Full Text PDFThe concentrations of 17 non-essential elements (Al, As, Ba, Be, Cd, Ce, Cr, Hg, La, Li, Pb, Sb, Sn, Sr, Th, Ti, and Tl) were determined in brown grain rice samples of two varieties: Fortuna and Largo Fino. The samples were collected from the four main producing regions of Corrientes province (Argentina). Quantitative determinations were performed by inductively coupled plasma mass spectrometry (ICP-MS), using a validated method.
View Article and Find Full Text PDFThis paper describes the determination and evaluation of the major and trace element composition (Al, As, Ba, Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Sr and Zn) of Sechium edule (Jacq) Swartz fruits collected from four different places of production in Corrientes province, Argentina. Element concentrations were determined by using inductively coupled plasma optical emission spectrometry (ICP OES) after microwave digestion. The accuracy was confirmed with standard reference material of spinach leaves (NIST, 1570a) and spiking tests.
View Article and Find Full Text PDFUnlabelled: Argentina is an important worldwide wine producer. In this country, there are several recognizable provinces that produce Sauvignon blanc wines: Neuquén, Río Negro, Mendoza, and San Juan. The analysis of the provenance of these white wines is complex and requires the use of expensive and time-consuming techniques.
View Article and Find Full Text PDFA new method for the simultaneous determination of amoxicillin trihydrate (AMT) and sodium diclofenac (DIC) in pharmaceutical formulations is proposed. The resolution of binary mixtures of these drugs has been accomplished by using partial least squares (PLS) regression analysis. The model was obtained from UV spectral data and validated by internal cross-validation; it was used to find the concentration of analytes in some commercial samples.
View Article and Find Full Text PDFIntroduction: The chemometric characterisation of two plants frequently used as food and medicinal species, Achyrocline satureioides and Achyrocline venosa (Asteraceae: Gnaphalieae), was carried out based on their mineral composition. Both species, known by the common name of 'marcelas', are very similar in their morphological features but they have different medicinal and food properties.
Objective: To develop multivariate models for the classification of A.
A new method to determine a mixture for sweetener sodium saccharin and aspartame in commercial noncaloric sweeteners is proposed. A classical full factorial design for standards was used in the calibration step to build the partial least-squares (PLS-2) model. Instrumental data were obtained by means of UV-visible spectrophotometry.
View Article and Find Full Text PDFMultielement analysis of lemon juices from different Argentinean regions was carried out by instrumental neutronic activation analysis (INAA) with the aim at developing a reliable method in the traceability of the origin of lemon juices. This work presents a characterization of 44 lemon juice samples selected from three different geographical origins in the Northwest region of Argentina. Multivariate chemometric techniques such principal component analysis and lineal discriminant analysis (LDA) were used with the aim of classifying the juices and identifying the most significant parameters.
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