Predicting lithium-ion battery degradation is worth billions to the global automotive, aviation and energy storage industries, to improve performance and safety and reduce warranty liabilities. However, very few published models of battery degradation explicitly consider the interactions between more than two degradation mechanisms, and none do so within a single electrode. In this paper, the first published attempt to directly couple more than two degradation mechanisms in the negative electrode is reported.
View Article and Find Full Text PDFProc Math Phys Eng Sci
June 2019
A one-dimensional model for the initiation of shear bands in a reactive material is developed, which accounts for thermal softening, strain hardening and strain-rate effects, and models the chemical reaction using an Arrhenius source term. An inhomogeneity in the heat flux is used as the stimulus for localized plastic deformation, and a solution is sought as a perturbation to the elastic solution. In the analysis, the thin zone of localization is identified as a boundary layer.
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