The Interaction of Waterborne Epoxy/Dicyandiamide Varnishes with Metal Oxides.

For delayed crosslinking of waterborne epoxy varnishes, dicyandiamide (DICY) is often used as a latent curing agent. While, for amine-based curing agents such as diaminoethane (DAE), chemical interactions with metal oxides are well described, so far, no studies have been performed for DICY and waterborne epoxy varnishes. Hence, in this work X-ray photoelectron spectroscopy (XPS) was used to investigate reactions of DICY and varnishes with technical surfaces of Al, Zn, and Sn.

Effect of Epoxy Structure on Properties of Waterborne Coatings and Electrical Steel Laminates.

Epoxy varnishes are of high relevance to advanced steel laminates for the transformation of electric energy. Structure-property correlations of epoxy varnishes, coil coatings and electrical steel laminates are poorly described. Hence, the main objective of this paper was to develop, implement and evaluate well-defined waterborne model epoxy varnishes for electrical steel laminates, and to elucidate structure-property correlations.

Comparison of Crosslinking Kinetics of UV-Transparent Ethylene-Vinyl Acetate Copolymer and Polyolefin Elastomer Encapsulants.

Encapsulants based on ethylene-vinyl acetate copolymers (EVA) or polyolefin elastomers (POE) are essential for glass or photovoltaic module laminates. To improve their multi-functional property profile and their durability, the encapsulants are frequently peroxide crosslinked. The crosslinking kinetics are affected by the macromolecular structure and the formulation with stabilizers such as phenolic antioxidants, hindered amine light stabilizers or aromatic ultraviolet (UV) absorbers.