The order of magnitude of increased growth, multiplication rate, and decreased sporulation of after exposure to nanotesla magnetic fields (MFs) relative to control samples were observed experimentally. Earth's total magnetic field intensity was reduced from 47.9 ± 0.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
July 2018
The purpose of this study was development of the optimal conditions for the inertization of the polluted marine sediments using groundwater treatment sludge highly enriched in iron and aluminum. For that purpose fine-grained sediment (>85% clay and silt fraction) highly enriched in copper and zinc was amended with the waste sludge (from 10% to 50%). The sample with the optimum percentage of the waste sludge was further subjected the thermal treatment at 200-800°C.
View Article and Find Full Text PDFSince the production of printed circuit boards (PCBs) generates wastewater contaminated with heavy metals and organic matter, PCB factories represent potential pollution sites. The wastewater toxicologically tested in this study contained several metals and the most abundant were copper and iron. At two exposure times tested (4 and 24 h) PCB wastewater (PCBW) proved to be cytotoxic (decreased cell viability) and genotoxic (increased comet assay tail intensity and tail moment) to human blood peripheral lymphocytes in vitro, and the oxidative stress parameter (malondialdehyde concentration) was also found to be higher.
View Article and Find Full Text PDFEcotoxicol Environ Saf
April 2015
Boats are washed periodically for maintenance in order to remove biofoulants from hulls, which results in the generation of wastewater. This study aimed at evaluating the cyto/genotoxic and mutagenic properties of wastewater produced by pressure washing of boats. The chemical characterisation of this wastewater showed that Cu, Zn, V, Cr, Fe, Pb, and select organic contaminants exceeded the maximum allowable values from 1.
View Article and Find Full Text PDFThe purpose of this work was detailed physicochemical, radiological, and toxicological characterization of the composite sample of water intended for human consumption in the Cameron/Tuba City abandoned uranium mining area before and after a combined electrochemical/advanced oxidation treatment. Toxicological characterization was conducted on human lymphocytes using a battery of bioassays. On the bases of the tested parameters, it could be concluded that water used for drinking from the tested water sources must be strictly forbidden for human and/or animal consumption since it is extremely cytogenotoxic, with high oxidative stress potential.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
December 2014
The purpose of this work was to develop a pilot plant purification system and apply it to groundwater used for human consumption, containing high concentrations of arsenic and increased levels of phosphates, ammonia, mercury and color. The groundwater used was obtained from the production well in the Vinkovci County (Eastern Croatia). Due to a complex composition of the treated water, the purification system involved a combined electrochemical treatment, using iron and aluminum electrode plates with simultaneous ozonation, followed by a post-treatment with UV, ozone and hydrogen peroxide.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
November 2014
The purpose of this work was development of a new method for the neutralization/purification of printed circuit boards wastewater (PCBW) originating from Zagreb, Croatia, using two industrial by-products. PCBW was characterized with low pH value (2.11) and high concentration of TDS (50190 mg L(-1)), copper (4190 mg L(-1)) and iron (2660 mg L(-1)).
View Article and Find Full Text PDFBackground: The main objective of the present study was to investigate chemical composition and possible cyto/genotoxic potential of several medical implant materials commonly used in total hip joint replacement.
Methods: Medical implant metal alloy (Ti6Al4V and CoCrMo) and high density polyethylene particles were analyzed by energy dispersive X-ray spectrometry while toxicological characterization was done on human lymphocytes using multi-biomarker approach.
Results: Energy dispersive X-ray spectrometry showed that none of the elements identified deviate from the chemical composition defined by appropriate ISO standard.
J Environ Sci Health A Tox Hazard Subst Environ Eng
October 2013
The aim of this research was development of new system for the treatment of highly polluted wastewater (COD = 10240 mg/L; SS = 2860 mg/L) originating from vine-making industry. The system consisted of the main treatment that included electrochemical methods (electro oxidation, electrocoagulation using stainless steel, iron and aluminum electrode sets) with simultaneous sonication and recirculation in strong electromagnetic field. Ozonation combined with UV irradiation in the presence of added hydrogen peroxide was applied for the post-treatment of the effluent.
View Article and Find Full Text PDFIn this research, toxicological safety of two newly developed methods for the treatment of landfill leachate from the Piškornica (Croatia) sanitary landfill was investigated. Chemical treatment procedure combined chemical precipitation with CaO followed by coagulation with ferric chloride and final adsorption by clinoptilolite. Electrochemical treatment approach included pretreatment with ozone followed by electrooxidation/electrocoagulation and final polishing by microwave irradiation.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2013
This article presents a pilot-plant study of the electroplating wastewater treatment by the processes of electroreduction with iron electrode plates, and electrocoagulation/ozonation with aluminum electrode set, followed by the process of ozonation. The initial effluent was found to be highly enriched in heavy metals and to possess the elevated levels of organic contaminants. The values of Cr(VI), Fe, Ni, Cu, Zn, Pb, TOC, and COD exceeded the upper permissible limits of 63, 220.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
July 2013
The aim of this work was the development and application of the pilot plant with the capacity of 1000 L/day for the purification of groundwater used for human consumption characterized with high concentration of arsenic and increased values of organic pollutants, ammonia, nitrites, color and turbidity. For that purpose, groundwater from the production wells supplying the towns Zrenjanin and Temerin (Vojvodina, Serbia) was used. Due to its complex composition, the purification system required the combination of the electroreduction/electrocoagulation, using iron and aluminum electrode plates with/without ozonation, followed by the electromagnetic treatment and the finally by the simultaneous ozonation/UV treatment.
View Article and Find Full Text PDFIn this study we compared three methods for the treatment of electroplating sludge highly loaded with zinc and iron: (1) calcium oxide-based solidification/stabilisation; (2) conversion into inert material by adsorption of organic and inorganic pollutants onto activated carbon; and (3) conversion of mobile waste components into insoluble phosphates. All three methods proved highly efficient in the conversion of hazardous waste into inert material. Under optimum treatment conditions zinc concentration in the leachate of solidified waste was reduced by 99.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2012
The aim of this research was development of appropriate procedure for the treatment of landfill leachate taken from the Visevac, Mraclinska Dubrava and Piskornica sanitary landfills. Due to the complex nature of the effluents a combined treatment approach was applied. The pretreatment step included simultaneous treatment with calcium oxide and electrocoagulation/electrooxidation by stainless steel electrode set.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2012
The subject of this study was chemical and radiological characterization of the fly and bottom ash, by-product of the combustion of coal used as an energy source in the former sulfate pulp factory in Plaški. The research involves determination of the concentration of macro, micro and trace elements and activities of the radionuclides in: (i) ash from different positions of the landfill; (ii) soil samples in the zone of the influence of the landfill; (iii) control soil samples and (iv) sediment sample from the river Dretulja. Besides, in situ measurement of an effective dose rate above ash/soil was also determined.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
October 2012
The present study aimed to characterize chemical properties of clay bricks containing 20 % of sewage sludge. After detection of potentially hazardous metals, we simulated precipitation exposure of such material to determine the amount of heavy metals that could leach out of the bricks. Metals, such as copper, zinc, nickel, cobalt, chromium, etc.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
August 2012
The purpose of this work was development and application of the purification system suitable for the treatment of the acid mine drainage (AMD) accumulated in the "Robule" Lake, which represents the part of the Bor copper mining and smelting complex, Serbia. The study was undertaken in order to minimize adverse effect on the environment caused by the discharge of untreated AMD, which was characterized with low pH value (2.63) and high concentration of heavy metals (up to 610 mg/L) and sulfates (up to 12,000 mg/L).
View Article and Find Full Text PDFThe aim of this study was to investigate the efficiency of (1) chemical precipitation by calcium oxide, (2) coagulation/flocculation by ferric chloride (FC), and (3) the combination these two methods in reducing the toxicity of wastewater generated by boat pressure washing. All three methods gave satisfactory results in the removal of colour, turbidity, Cr, Fe, Cu, Zn, and Pb. The concentrations of heavy metals were lowered below national limits with 1 g of CaO, 2.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
May 2012
A combined treatment approach using advanced oxidation, electrochemical methods and microwaves was developed and applied for the treatment of landfill leachate taken from Piskornica (Koprivnica, Croatia) sanitary landfill. Due to the complex nature of the effluent and extremely low bio-degradability (BOD(5)/COD ratio = 0.01) the purification of the leachate started with pre-treatment with ozone followed by simultaneous ozonation and electrocoagulation/electrooxidation using the set of iron and aluminum electrodes, and finally, the degradation of organic residue and ammonia with microwaves.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
March 2012
The purpose of this work was development and application of the purification system suitable for the treatment of groundwater used for human consumption, satisfying following criteria: (a) no need for external addition of the chemicals; (b) simultaneous removal of wide range of contaminants present in the treated water; (c) low sensitivity to the changes in the composition of the treated water; (d) high quality of treated water with regards to all measured parameters. Therefore the well water from the 60 m deep water layer situated near the city of Osijek (Eastern Croatia) with elevated values of heavy metals, color, turbidity, suspended solids, ammonia and organic contaminants was processed. Due to the complex composition of the treated water, the purification system required the combination of electroreduction/electrocoagulation, using iron and aluminum electrode plates followed by the simultaneous ozonation/UV treatment.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
February 2012
This paper provides the information on the optimum conditions of the treatment process of the boat pressure washing wastewater (BPWW) by the combination of the ozonation and electrochemical (EC) methods developed on the laboratory and pilot plant scale. The initial effluent was highly enriched in heavy metals and elevated levels of organic contaminants. The concentrations of V, Cr, Fe, Cu, Zn, TOC, and COD exceeded the upper permissible limits of 22, 20, 6, 112, 17, 4, and 2 times, respectively.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
August 2011
The purpose of this research was the characterization and improvement of the quality of water used for human consumption of unregulated/regulated water sources located in the Cameron/Tuba City abandoned uranium mining area (NE Arizona, western edge of the Navajo Nation). Samples were collected at six water sources which included regulated sources: Wind Mill (Tank 3T-538), Badger Springs and Paddock Well as well as unregulated sources: Willy Spring, Water Wall and Water Hole. Samples taken from Wind Mill, Water Wall and Water Hole were characterized with high turbidity and color as well as high level of manganese, iron and nickel and elevated value of molybdenum.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2011
The aim of this research was development of appropriate procedure for treatment of landfill leachate taken from old sanitary landfill Piskornica (Koprivnica, Croatia). Due to complex nature of the effluent a combined treatment approach was applied. Samples were treated with calcium oxide followed by ferric chloride and finally with clinoptilolite.
View Article and Find Full Text PDF