Broadband high-resolution multi-species CARS in gas-filled hollow-core photonic crystal fiber.

We report the use of coherent anti-Stokes Raman spectroscopy (CARS) in gas-filled hollow-core photonic crystal fiber (HC-PCF) for trace gas detection. The long optical path-lengths yield a 60 dB increase in the signal level compared with free-space arrangements. This enables a relatively weak supercontinuum (SC) to be used as Stokes seed, along with a ns pump pulse, paving the way for broadband (>4000  cm) single-shot CARS with an unprecedented resolution of ∼100  MHz.