Comparison of headspace solid-phase microextraction high capacity fiber coatings based on dual mass spectrometric and broadband vacuum ultraviolet absorption detection for untargeted analysis of beer volatiles using gas chromatography.

Despite the same basic ingredients used in brewing, there is a significant variation in beer styles. With the rapid increase in craft brewing, beer styles have become even more numerous and complex in the recent past. A GC-MS/VUV (post-column split for dual detection) instrument with headspace high capacity SPME was used to investigate 21 different beers which represent three beer styles - India pale ales, blondes, and hefeweizens.

On-line sample preparation for multiclass vitamin, hormone, and mycotoxin determination in chicken egg yolk using LC-MS/MS.

Hen egg yolk from chicken eggs were examined for their mycotoxin, hormone, and fat-soluble vitamin content. A method was developed for multi-class analysis of egg yolk using a dilute/precipitate, centrifuge, and shoot process coupled with on-line sample clean-up using restricted access media with LC-MS/MS. Matrix effects were evaluated and a standard addition protocol with internal standards was chosen for analyte quantitation.

Characterization of ethoxylated alcohols in friction reducers using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry.

Rationale: Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) provides detailed information for the analysis of ethoxylated alcohols and polymers. In this study, five friction reducers used in commercial hydraulic fracturing processes were analyzed in their as-received form to identify their ethoxylated alcohol content. The friction reducers were then subjected to lab-simulated downhole conditions.