Photonic and plasmonic surface field distributions characterized with normal- and oblique-incidence multi-photon PEEM.

Photonic and plasmonic fields at surfaces can have complicated spatial distributions, which are reflected in the corresponding photoelectron yields imaged in PEEM. These can include the intricate moiré patterns on the surfaces of photonic and plasmonic structures and bright fringe field patterns at their edges. Understanding field distributions requires an understanding of how the guided modes develop, propagate, and interfere with each other and with the incident far-field light.

Mode structure of planar optical antennas on dielectric substrates.

We report a numerical study, supported by photoemission electron microscopy (PEEM), of sub-micron planar optical antennas on transparent substrate. We find these antennas generate intricate near-field spatial field distributions with odd and even numbers of nodes. We show that the field distributions are primarily superpositions of planar surface plasmon polariton modes confined to the metal/substrate interface.

Light propagation and interaction observed with electrons.

We discuss possibilities for a microscopic optical characterization of thin films and surfaces based on photoemission electron microscopy. We show that propagating light with wavelengths across the visible range can readily be visualized, and linear and non-linear materials properties can be evaluated non-invasively with nanometer spatial resolution. While femtosecond temporal resolution can be achieved in pump-probe-type experiments, the interferometric approach presented here has typical image frame times of ~200 fs.

Direct coupling of photonic modes and surface plasmon polaritons observed in 2-photon PEEM.

We report the direct microscopic observation of optical energy transfer from guided photonic modes in an indium tin oxide (ITO) thin film to surface plasmon polaritons (SPP) at the surfaces of a single crystalline gold platelet. The photonic and SPP modes appear as an interference pattern in the photoelectron emission yield across the surface of the specimen. We explore the momentum match between the photonic and SPP modes in terms of simple waveguide theory and the three-layer slab model for bound SPP modes of thin metal films.

Electrophoretic mobility of sarcoplasmic reticulum vesicles - analytical model includes amino acid residues of A+P+N domain of Ca(2+)-ATPase and charged lipids.

This work is an experimental and theoretical study of electrostatic and hydrodynamic properties of the surface of sarcoplasmic reticulum (SR) membrane using particle electrophoresis. The essential structural components of SR membrane include a lipid matrix and a dense layer of Ca(2+)-ATPases embedded in the matrix. The Ca(2+)-ATPase layer both drives and impedes vesicle mobility.

Electrophoretic mobility of sarcoplasmic reticulum vesicles is determined by amino acids of A+P+N domains of Ca2+-ATPase.

Establishing the origin of electrophoretic mobility of sarcoplasmic reticulum (SR) vesicles is the primary goal of this work. It was found that the electrophoretic mobility originates from ionizable amino acids of cytoplasmic domains of the Ca2+-ATPase, the calcium pump of SR. The mobility was measured at pH 4.

5.4 nm spatial resolution in biological photoemission electron microscopy.

We report a spatial resolution of 5.4 nm in images of sarcoplasmic reticulum from rabbit muscle. The images were obtained in an aberration-corrected photoemission electron microscope with a hyperbolic mirror as the correcting element for spherical and chromatic aberration.

Flexible inorganic nanowire light-emitting diode.

We report a highly flexible light-emitting device in which inorganic nanowires are the optically active components. The single-crystalline ZnO nanowires are grown at 80 degrees C on flexible polymer-based indium-tin-oxide-coated substrates and subsequently encapsulated in a minimal-thickness, void-filling polystyrene film. A reflective top contact serving as the anode in the diode structure is provided by a strongly doped p-type polymer and an evaporated Au film.

Environmental swap energy and role of configurational entropy in transfer of small molecules from water into alkanes.

We studied the effect of segmented solvent molecules on the free energy of transfer of small molecules from water into alkanes (hexane, heptane, octane, decane, dodecane, tetradecane, and hexadecane). For these alkanes we measured partition coefficients of benzene, 3-methylindole (3MI), 2,3,4,6-tetrachlorophenol (TeCP), and 2,4,6-tribromophenol (TriBP) at 3, 11, 20, 33 [corrected], and 47 degrees C. For 3MI, TeCP, and TriBP the dependence of free energy of transfer on length of alkane chains was found to be very different from that for benzene.