Publications by authors named "Rivelino M Cavalcante"

Article Synopsis
  • This study systematically reviews methods for extracting and analyzing organic contaminants in crab urine, which are essential due to crabs' role as bioindicators of aquatic contamination.
  • Although harmful substances like PCBs and pesticides are known to affect ecosystems, most studies have focused mainly on PAHs, leaving a significant research gap.
  • The perception that collecting crab urine is difficult, along with insufficient methodologies in existing literature, highlights the need for more extensive research to improve ecological understanding and environmental monitoring efforts.
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Article Synopsis
  • The study focused on analyzing tarballs that contaminated the Brazilian coast in late 2022 using forensic environmental geochemistry techniques.
  • Gas chromatography and FT-ICR mass spectrometry were employed to identify distinct biomarkers in tarball samples from five Brazilian states, revealing they shared a common source but differed from previous oil spills in 2019 and 2022.
  • The analysis indicated that the tarballs were made from mature marine crude oil, showed low weathering, and likely came from ship tank washings, suggesting their potential for long-term environmental impact.
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Identifying the origin of plastic pollution is essential for the development of effective preventive and mitigatory strategies and guidelines for companies, governments, and stakeholders. In 2022, a considerable amount of plastic waste stranded on beaches of the northeastern coast of Brazil. A preliminary analysis of this waste revealed that most of the items were likely foreign made, and a brand auditing approach was applied to identify the brands, parent companies, and potential origin of the plastic waste.

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Soil contamination by heavy metals (HM) from pesticides poses a serious environmental threat, affecting sustainability and agricultural productivity. Soil enzymes are essential for biochemical reactions such as organic matter decomposition and nutrient cycling and are vital for maintaining soil health. However, the effects of HM on soil enzyme activity are not yet well understood.

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The Equatorial South Atlantic region, spanning over 1700 km, is currently undergoing extensive exploitation through various activities such as oil extraction, desalination plants, marine mineral explorations, and wind power for green hydrogen production. This undoubtedly also contributes to the exacerbation of pre-existing chronic environmental impacts. This study aims to investigate the concentrations of 60 substances, categorized as Persistent Organic Pollutants (POPs) and Contaminants of Emerging Concern (CECs) from various classes including: polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), organochlorine pesticides (OCPs), as well as Pyrethroids (PPs), Triazines (TPs) and Organophosphates (OPPs) pesticides in consumable fish, shellfish, and crabs.

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The São Francisco River, significant in semi-arid areas, faces impacts from hydroelectric plants and agricultural pesticides. Despite extensive research on its aquatic life, especially fish reproductive biology, there's a notable lack of studies on toxicity and its human health implications. This gap highlights the need for targeted research in this vital ecological zone.

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In the present study, we applied forensic geochemistry to investigate the origin and fate of spilled oils like tarballs stranded at the beaches of Bahia, in northeastern Brazil, in September 2023, based on their fingerprints. Saturated and aromatic compounds were assessed by gas chromatography, and the oceanic surface circulation patterns were deciphered to determine the geographic origin of the spill. Contamination by petroleum represents an enormous threat to the unique, species-rich ecosystems of the study area.

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Sea turtle mortality is often related to materials that reach the coast from different anthropic activities worldwide. This study aimed to investigate whether sea turtle mortality was related to older marine problems, such as solid waste, or one of the largest oil spill accidents on the Brazilian coast, that occurred in 2019. We posed three questions: 1) Are there solid residues in the digestive tract samples, and which typology is the most abundant? 2) Can meso‑ and macro-waste marine pollutants cause mortality? 3) Is the dark material found really oil? A total of 25 gastrointestinal content (GC) samples were obtained, of which 22 ingested waste of anthropogenic origin and 18 were necropsied.

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The Parnaíba River is the main river in the Parnaíba Delta basin, the largest delta in the Americas. About 18 polycyclic aromatic hydrocarbons (PAHs) were identified and the environmental risk associated with the sediments was evaluated. The study found that PAHs levels ranged from 5.

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Coastal ecosystems are facing increasing anthropogenic stressors, including rapid urbanization rates and extensive fossil fuel usage. Nevertheless, the distribution of hydrocarbons in the Brazilian semi-arid region remains relatively uncharacterized. In this study, we analyzed ten surface sediment samples (0-2 cm) along the banks of the Acaraú River to assess the chronic contributions of aliphatic and aromatic hydrocarbons.

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Since the 2019 oil spill on the northeastern coast of Brazil, oil materials have washed up on the beaches. A characteristic of the recent oil spill that began in late August was that some of the oiled material, such as tarballs, contained the goose barnacle species Lepas anatifera (Cirripedia, Lepadomorpha), which is well-known for its cosmopolitan distribution and wide occurrence in the oceans. The findings of this study provide information on the occurrence and contamination of petroleum hydrocarbons in animals adhered to the surfaces of tarballs sampled from beaches in the Brazilian states of Ceará and Rio Grande do Norte, between September and November 2022.

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The Ocean decade (2021-2030) for sustainable development proclaimed in 2017 by the UN, seeks to promote and conserve the sustainable use of oceans, seas, and marine resources. For this, the distribution of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), and biomarkers, in sediments from the Fortaleza coastal zone (Mucuripe harbor (MH) and Inner Continental shelf (ICS)) were used to assess the impacts of anthropogenic activities in the area. The concentrations of total n-alkanes (Σ16 n-alkanes) in MH and ICS sediments varied from 35.

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The main objective of this study was to investigate the 2019 and 2022 oil spill events that occurred off the coast of the State of Ceará, Northeastern Brazil. To further assess these mysterious oil spills, we investigated whether the oils stranded on the beaches of Ceará in 2019 and 2022 had the same origin, whether their compositional differences were due to weathering processes, and whether the materials from both were natural or industrially processed. We collected oil samples in October 2019 and January 2022, soon after their appearance on the beaches.

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In this study, the multi-marker approach was used for the first time with a highly urbanized lake located in the city of Fortaleza, Brazil, to provide a comprehensive view of temporal trends in sources of pollutants and evaluate the relation between the influence of anthropogenic activities and socioeconomic development. Total concentrations of the markers analyzed ranged from 21.0 to 103.

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The Jundiaí-Potengi Estuary (EJP) is located on the semi-arid coast of northeastern Brazil and is influenced by multiple sources of contamination. The sediment quality of EJP was assessed by using a multi-geochemical approach during the dry and wet seasons. Sediments were analyzed for concentrations of nutrients, metals, polycyclic aromatic hydrocarbons (PAHs), pesticides, hormones (natural and synthetic), and sterols.

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Sterols and endocrine-disrupting chemicals were analyzed in two dated sediment cores collected in the Jaguaribe river to determine the recent decades' influence of urbanization and agropastoral activities on the inputs of fecal pollution in a semi-arid region of Brazil. Stigmasterol and sitosterol were the most abundant of the 6 sterols examined in both cores, indicating an important contribution of organic matter from mangrove forests to the study region. Coprostanol presented a continuous increase in concentrations from the 1930s to the 2000s in one core, however, showing higher concentrations (>100 ng g) in the upper layers of both cores.

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This article presents a synthesis of information about the massive oil spill in Brazil (2019/2020). The event affected 11 states; however, the majority of the oil residue was collected (~ 5380 tons) near nine states (99.8%) in northeastern Brazil.

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We reviewed 20 years of levels, sources, and environmental risks related to the main petroleum hydrocarbons in the northeast region of Brazil. The aim of this study was to conduct a systematic review to serve as a comprehensive baseline for future monitoring programmes related to the oil spill disaster in 2019/2020. Most contamination levels of both PAHs and AHs were classified as low, except those in specific areas influenced by human activities, such as ports, highly urbanised mangroves, or rivers of medium-sized cities with inadequate liquid and solid waste treatment.

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The year 2020 was atypical due to the pandemic caused by the SARS-CoV-2 virus (COVID-19), providing a unique opportunity to understand changes in air quality due to the reduction in urban activity. Therefore, the aim of the present study was to perform an integrated evaluation on the influence of the effects of the 2020 pandemic on air quality in the city of Fortaleza, investigating levels of PM, PM, NO, NO, SO, CO, and O, corresponding health risks, as well as the influence of meteorological variables and urban activity. In all phases analyzed, significant reductions were found in NO, NO, NO, and CO.

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Recent studies have shown that the effectiveness of establishing Marine Protected Areas (MPAs) is threatened by toxic effects of contaminants. São Paulo is the most economically developed state of Brazil, and its coast is protected by a system of MPAs, including the North Shore Marine Protected Area (NSMPA). The present study provides a first assessment of sediment quality in NSMPA and two reference sites.

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In 2018, unidentified packages appeared along approximately 1600 Km of the Brazilian coastline causing widespread pollution to beaches and danger to society. The packages were found to be bales of raw rubber ranging in size from 0.06 m³ to 3.

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The International Agency for Research on Cancer (IARC) classifies benzene in group 1 (carcinogenic to humans). Particulate matter (PM) has recently also been classified in this category. This was an advance toward prioritizing the monitoring of particles in urban areas.

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The contribution of vehicle emissions to air pollution is considered a large environmental and health problem in big Brazilian cities caused, among other factors, by slow renewal of the old vehicle fleet. Brazilian studies usually only consider traffic-related issues in transportation analysis, with minor assessments of emissions and close to non-existent assessment of air quality. On this background, this research aimed to calibrate and evaluate the Operational Street Pollution Model (OSPM®) to Brazilian conditions by implementing Brazilian emission factors.

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The aim of the present study was to perform the first assessment of the abundance and classification of marine debris as well as determine the sources, transport and fate of this debris on an urbanized coast with multiple human activities. More than 80% of the marine debris was composed of synthetic materials. The beached marine debris was classified according to size.

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18 polycyclic aromatic hydrocarbons (PAHs) were evaluated in the Jaguaribe River to explore the influence of grain size, organic carbon, humic and fulvic acids and black carbon on their adsorption onto sediment. The ∑PAHs concentrations variated from 0.6 to 3752.

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