Nano particles of a few α/β BiO hetero-junctions of various compositions synthesized by one- pot hydrothermal method, exhibit exceptional and synergistic photo-catalytic activity for the degradation of Rhodamine-B in aqueous solution under natural sunlight. Pure α and pure β BiO are also synthesized by control post heating of synthesized hetero-junction. The nano-materials were characterized by diffraction (XRD), microscopic and spectroscopic techniques.
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