Combining QSAR and SSD to predict aquatic toxicity and species sensitivity of pyrethroid and organophosphate pesticides.

The widespread use of pyrethroid and organophosphate pesticides necessitates accurate toxicity predictions for regulatory compliance. In this study QSAR and SSD models for six pyrethroid and four organophosphate compounds using QSAR Toolbox and SSD Toolbox have been developed. The QSAR models, described by the formula 48 h-EC50 or 96 h-LC50 = x + y * log Kow, were validated for predicting 48 h-EC50 values for acute toxicity and 96 h-LC50 values for acute fish toxicity, meeting criteria of ≥10, ≥0.

Recovery targets and timescales for Lough Neagh and other lakes.

The framework, model and methods of Nürnberg were applied and evaluated in Lough Neagh and 19 other lakes in order to establish inflow phosphorus concentrations that support target lake values. Supporting concentrations, in the absence of an internal load, were derived and the effect of uncertainty in the model retention coefficient was relatively small, ±11-20 % in Lough Neagh and an average (n = 17) of ±9.7 % in the other lakes.

Timescale of reduction of long-term phosphorus release from sediment in lakes.

It is important for lake management and policy to estimate the timescale of recovery from long-term P release from sediment after a reduction in the external load. To provide a scientific basis for this, a condensed model was elaborated, applied and evaluated in four lakes. The model is based on first order kinetics, with an overall rate constant composed of the rate of diagenesis of labile P (kd,2) and rate of burial of P (kb) below an active sediment layer.

Assessing lake ecological status across a trophic gradient through environmental and biological variables.

The Water Framework Directive was widely welcomed because it sought to integrate chemical and biological elements of aquatic ecosystems to achieve 'good ecological status', reflecting at most slight anthropogenic impact. However, implementation has been criticised because of the failure to adequately integrate these elements and assess status of the whole ecosystem. In this study, a suite of environmental and biotic variables was measured to assess their relative importance as predictors of lake status for 50 lakes in the north of the island of Ireland.

Metal to phosphorus stoichiometries for freshwater phytoplankton in three remote lakes.

Simultaneous measurements of changes in phytoplankton biomass and the metal and phosphorus (P) content of cells have been captured to attest to metal to P stoichiometries for freshwater phytoplankton. Three Scottish lakes that had received high, medium or low metal contamination from the atmosphere were selected for study. Phytoplankton cells were collected and Inductively Coupled Plasma-Mass Spectrometry was used to measure their lead (Pb), cadmium (Cd), mercury (Hg), copper (Cu), zinc (Zn), nickel (Ni), chromium (Cr), manganese (Mn), cobalt (Co) and P content.

The Applicability of the Distribution Coefficient, KD, Based on Non-Aggregated Particulate Samples from Lakes with Low Suspended Solids Concentrations.

Separate phases of metal partitioning behaviour in freshwater lakes that receive varying degrees of atmospheric contamination and have low concentrations of suspended solids were investigated to determine the applicability of the distribution coefficient, KD. Concentrations of Pb, Ni, Co, Cu, Cd, Cr, Hg and Mn were determined using a combination of filtration methods, bulk sample collection and digestion and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Phytoplankton biomass, suspended solids concentrations and the organic content of the sediment were also analysed.

An assessment of toxicity in profundal lake sediment due to deposition of heavy metals and persistent organic pollutants from the atmosphere.

A Tier I Sediment Ecological Risk Assessment of profundal lake sediment contaminated by diffuse pollution of heavy metals and POPs deposited from the atmosphere was completed. The concentrations of seven heavy metals and four groups of POPs (OCs, PCBs, PAHs, PBDEs) were determined in the profundal sediment of ten lakes in the United Kingdom and two sediment toxicity tests completed (chironomid survival and emergence and cladoceran survival and reproduction). The results showed that around half the lakes are at least moderately contaminated by Pb, Zn, Cd, As and PAHs deposited from the atmosphere and the toxicity quotient suggests that the contaminants of concern are Pb, As and PAHs, and not the other metals nor OCs and PCBs.

Developing an optimal river typology for biological elements within the Water Framework Directive.

The Water Framework Directive requires a river classification based on environmental variables (a typology) to be created as a structure for reporting ecological status. A single permutation procedure, utilising the same variables repeatedly but with different categorical divisions, enabled both the choice of variables and the boundary divisions for these variables to be optimised simultaneously in the development of the typology. This, in addition to a data set which appropriately combined different biological elements, enabled a typology to be developed which was far more effective than a System A, CCA-derived or expert opinion-based typology in segregating communities.

Lake sedimentary evidence of phosphorus, iron and manganese mobilisation from intensively fertilised soils.

A study of historical P inputs to Friary Lough, Co. Tyrone, Northern Ireland used a multi-sediment core approach. One of the sediment cores taken from the littoral zone at 2.

The 20th century whole-basin trophic history of an inter-drumlin lake in an agricultural catchment.

Eight 1-m sediment cores were extracted from across the basin of Friary Lough, a 5.4-ha eutrophic lake in a wholly grassland agricultural catchment in Co. Tyrone, Northern Ireland.

The historical record of PAH, PCB, trace metal and fly-ash particle deposition at a remote lake in north-west Scotland.

Sediment cores taken from the deep basin of Loch Coire nan Arr in north-west Scotland were dated using 210Pb calibrated spheroidal carbonaceous particle (SCP) profiles and analysed for trace metals, polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). These data show that the site is one of the least contaminated by atmospheric pollution in the UK. Peak concentrations of PAHs were found to be equivalent to background values at sites in the English Lake District.

Modeling diffuse phosphorus loads from land to freshwater using the sedimentary record.

Diffuse phosphorus (P) loads to a small lake, Friary Lough, in a 1 km2 agricultural subcatchment were quantified over 90 years using a palaeolimnological model. The model assumes that lake total phosphorus (TP) is lost to the sediments and to the lake outflow during periods of steady-state or is also stored within the water column during periods of non-steady-state behavior. Reconstructed TP loads during the 1991-1995 time interval of 2.