Thermal noise and mechanical loss of SiO/TaO optical coatings at cryogenic temperatures.

Mechanical loss of dielectric mirror coatings sets fundamental limits for both gravitational wave detectors and cavity-stabilized optical local oscillators for atomic clocks. Two approaches are used to determine the mechanical loss: ringdown measurements of the coating quality factor and direct measurement of the coating thermal noise. Here we report a systematic study of the mirror thermal noise at 4, 16, 124, and 300 K by operating reference cavities at these temperatures.

Demonstration of a Timescale Based on a Stable Optical Carrier.

We report on the first timescale based entirely on optical technology. Existing timescales, including those incorporating optical frequency standards, rely exclusively on microwave local oscillators owing to the lack of an optical oscillator with the required frequency predictability and stability for reliable steering. We combine a cryogenic silicon cavity exhibiting improved long-term stability and an accurate ^{87}Sr lattice clock to form a timescale that outperforms them all.

X-ray total scattering study of magic-size clusters and quantum dots of cadmium sulphide.

Four types of magic-size CdS clusters and three different CdS quantum dots have been studied using the technique of X-ray total scattering and pair distribution function analysis. We found that the CdS quantum dots could be modelled as a mixed phase of atomic structures based on the two bulk crystalline phases, which is interpreted as representing the effects of random stacking of layers. However, the results for the magic-size clusters are significantly different.

Sustainable Chitin Nanofibrils Provide Outstanding Flame-Retardant Nanopapers.

Sustainable polysaccharide nanofibrils formed from chitin or cellulose are emerging biobased nanomaterials for advanced materials requiring high mechanical performance, barrier properties, for bioactive materials, or other functionalities. Here, we demonstrate a single-step, waterborne approach to prepare additive-free flame-retardant and self-extinguishing, mechanical high-performance nanopapers based purely on surface-deacetylated chitin nanofibrils (ChNFs). We show that the flammability can be critically reduced by exchanging the counterions, e.

Ultrastable Silicon Cavity in a Continuously Operating Closed-Cycle Cryostat at 4 K.

We report on a laser locked to a silicon cavity operating continuously at 4 K with 1×10^{-16} instability and a median linewidth of 17 mHz at 1542 nm. This is a tenfold improvement in short-term instability, and a 10^{4} improvement in linewidth, over previous sub-10-K systems. Operating at low temperatures reduces the thermal noise floor and, thus, is advantageous toward reaching an instability of 10^{-18}, a long-sought goal of the optical clock community.

A Simply Synthesized, Tough Polyarylene with Transient Mechanochromic Response.

A simple and high-yielding route to tough polyarylenes of the type poly(meta,meta,para-phenylene) (PmmpP) is developed. PmmpP is tough even in its as-synthesized state which has an intermediate molar mass of M ≈60 kg mol and exhibits outstanding mechanical properties at further optimized molecular weight of M =96 kg mol , E=0.9 GPa, ϵ=300 %.

1.5 μm Lasers with Sub-10 mHz Linewidth.

We report on two ultrastable lasers each stabilized to independent silicon Fabry-Pérot cavities operated at 124 K. The fractional frequency instability of each laser is completely determined by the fundamental thermal Brownian noise of the mirror coatings with a flicker noise floor of 4×10^{-17} for integration times between 0.8 s and a few tens of seconds.

Ultrastable laser with average fractional frequency drift rate below 5 × 10⁻¹⁹/s.

Cryogenic single-crystal optical cavities have the potential to provide high dimensional stability. We have investigated the long-term performance of an ultrastable laser system that is stabilized to a single-crystal silicon cavity operated at 124 K. Utilizing a frequency comb, the laser is compared to a hydrogen maser that is referenced to a primary caesium fountain standard and to the 87Sr optical lattice clock at Physikalisch-Technische Bundesanstalt (PTB).

Reduction of residual amplitude modulation to 1 × 10⁻⁶ for frequency modulation and laser stabilization.

Active control and cancellation of residual amplitude modulation (RAM) in phase modulation of an optical carrier is one of the key technologies for achieving the ultimate stability of a laser locked to an ultrastable optical cavity. Furthermore, such techniques are versatile tools in various frequency modulation-based spectroscopy applications. In this Letter we report a simple and robust approach to actively stabilize RAM in an optical phase modulation process.

Atomic clocks with suppressed blackbody radiation shift.

We develop a concept of atomic clocks where the blackbody radiation shift and its fluctuations can be suppressed by 1-3 orders of magnitude independent of the environmental temperature. The suppression is based on the fact that in a system with two accessible clock transitions (with frequencies ν1 and ν2) which are exposed to the same thermal environment, there exists a "synthetic" frequency ν(syn) ∝ (ν1 - ε12ν2) largely immune to the blackbody radiation shift. For example, in the case of 171Yb+ it is possible to create a synthetic-frequency-based clock in which the fractional blackbody radiation shift can be suppressed to the level of 10(-18) in a broad interval near room temperature (300±15  K).

Critical parameters for the scale-up synthesis of quantum dots.

The optical properties of quantum dots strongly depend on the synthesis conditions including the reagent grade of the chemicals. We developed a synthesis set-up allowing the reproducible preparation of quantum dots with a high control over chemical and physical parameters. Here, we report on the effects of the injection speed, the stirring velocity and the reagent grade of the chemicals on the photoluminescence behaviour of CdSe quantum dots.

Bose-Einstein condensation of alkaline earth atoms: ;{40}Ca.

We have achieved Bose-Einstein condensation of ;{40}Ca, the first for an alkaline earth element. The influence of elastic and inelastic collisions associated with the large ground-state s-wave scattering length of ;{40}Ca was measured. From these findings, an optimized loading and cooling scheme was developed that allowed us to condense about 2 x 10;{4} atoms after laser cooling in a two-stage magneto-optical trap and subsequent forced evaporation in a crossed dipole trap within less than 3 s.

Collisional losses, decoherence, and frequency shifts in optical lattice clocks with bosons.

We have quantified collisional losses, decoherence and the collision shift in a one-dimensional optical lattice clock on the highly forbidden transition (1)S(0)-(3)P(0) at 698 nm with bosonic (88)Sr. We were able to distinguish two loss channels: inelastic collisions between atoms in the upper and lower clock state and atoms in the upper clock state only. Based on the measured coefficients, we determine the operation parameters at which a 1D-lattice clock with (88)Sr shows no degradation due to collisions on the fractional uncertainty level of 10(-16).

Blue luminescence and superstructures from magic size clusters of CdSe.

In this letter, we present a low-temperature synthesis route revealing a new type of ultrasmall CdSe nanoparticle family with exceptional narrow blue emissions between 437 and 456 nm and full width at half-maxima below 20 nm. Transmission electron microscopy characterization shows the uniformity of the nanoparticles, which have a diameter of 1.6 nm.

Subkilohertz enhanced-power diode-laser spectrometer in the visible.

We report on a high-performance diode-laser spectrometer operating near 657 nm with narrow linewidth (<0.6 kHz) , enhanced power (as much as 40 mW), and low drift (<10 Hz/s) . The spectrometer comprised an extended-cavity diode-laser frequency stabilized to a high-finesse optical resonator and a broad-area antireflection coated laser diode as an amplifier with a single-lobe emission pattern of good spatial purity.

Calibration of a Shack-Hartmann sensor for absolute measurements of wavefronts.

We demonstrate a method with which to calibrate a Shack-Hartmann sensor for absolute wavefront measurement of collimated laser beams. Nearly perfect spherical wavefronts originating from a single-mode fiber were used as references. After the calibration, the uncertainty of the wavefront was less than lambda/100 peak to valley across a diameter of 6 mm.

Optical clock with ultracold neutral atoms.

We demonstrate how to realize an optical clock with neutral atoms that is competitive to the currently best single ion optical clocks in accuracy and superior in stability. Using ultracold atoms in a Ca optical frequency standard, we show how to reduce the relative uncertainty to below 10(-15). We observed atom interferences for stabilization of the laser to the clock transition with a visibility of 0.

Doppler cooling and trapping on forbidden transitions.

Ultracold atoms at temperatures close to the recoil limit have been achieved by extending Doppler cooling to forbidden transitions. A cloud of (40)Ca atoms has been cooled and trapped to a temperature as low as 6 microK by operating a magnetooptical trap on the spin-forbidden intercombination transition. Quenching the long-lived excited state with an additional laser enhanced the scattering rate by a factor of 15, while a high selectivity in velocity was preserved.

Photoassociation of cold Ca atoms.

We present the first measurement of a photoassociative spectrum of an alkaline earth element near the dissociation limit. The observed spectrum of Ca2 formed from cold atoms shows the regular vibrational series with the characteristic spacing of the 1/R3 asymptotic potential. The interpretation is in principle simplified compared to previous measurements on alkali metals by the nondegenerate ground state and the missing hyperfine structure of 40Ca.

Simultaneous cw laser emission including a Raman line of a He-Ne laser at six wavelengths in the visible range.

Simultaneous cw laser emission has been observed in a He-Ne discharge at 611.8-, 629.3-, 632.