Publications by authors named "Richard E Farrell"

Agriculture is an important contributor to NO emissions - a potent greenhouse gas - with high peaks occurring when soil mineral nitrogen (N) is high (e.g., after mineralization of organic N and N fertilizer application).

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Petroleum hydrocarbon (PHC) degradation slows significantly during the winter which substantially increases the time it takes to remediate soil in Arctic landfarms. The aim of this laboratory trial was to assess the potential of a meat and bonemeal (MBM) biochar to stimulate PHC degradation in contaminated soil collected from Iqaluit, Canada. Over 90 days, 3% (w/w) MBM biochar significantly increased F3- (equivalent nC-C) PHC degradation rate constants (k) in frozen soils when compared to the fertilizer (urea and monoammonium phosphate) control.

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Anthropogenic activities at the HudBay Minerals, Inc., Flin Flon (Manitoba, Canada) mining and processing facility have severely affected the surrounding boreal forest ecosystem. Soil contamination occurred via a combination of metal and sulfuric acid deposition and has resulted in forest dieback and ineffective natural recovery.

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Article Synopsis
  • HudBay Minerals has been involved in mining Zn and Cu in Flin Flon, MB since the 1930s, causing significant metal contamination and soil degradation in the surrounding boreal forest ecosystem.
  • Contaminated soils show distinct Zn speciation linked to two soil types: Group I with franklinite in weathered bedrock positions, and Group II stabilized by invasive metal-tolerant grasses, where Zn is found in various oxide complexes.
  • Despite high Zn levels in Group II soils promoting metal-tolerant plant growth, the overall soil properties and effects of erosion hinder the regeneration of native boreal forest species.
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Risk assessments often do not quantify the risk associated with soil inhalation. This pathway generally makes a negligible contribution to the cumulative risk, because soil ingestion is typically the dominant exposure pathway. Conditions in northern or rural centers in Canada characterized by large areas of exposed soil, including unpaved roads, favor the resuspension of soil particles, making soil inhalation a relevant risk pathway.

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Nitrous oxide (N(2)O) is a greenhouse gas with a global warming potential far exceeding that of CO(2). Soil N(2)O emissions are a product of two microbially mediated processes: nitrification and denitrification. Understanding the effects of landscape on microbial communities, and the subsequent influences of microbial abundance and composition on the processes of nitrification and denitrification are key to predicting future N(2)O emissions.

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The standard method of soft X-ray beamline calibration at the N K-edge uses the nu = 0 peak transition of gas-phase N(2). Interstitial N(2) gas trapped or formed within widely available solid-state ammonium- and amine-containing salts can be used for this purpose, bypassing gas-phase measurements. Evidence from non-nitrogen-containing compounds (KH(2)PO(4)) and from He-purged ammonium salts suggest that production of N(2) gas is through beam-induced decomposition.

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The soil bacterium Sphingomonas yanoikuyae was isolated from a petroleum-contaminated soil and grown on mineral salts agar overlaid with the polycyclic aromatic hydrocarbon phenanthrene. The effect of white mustard, Sinapis alba, on phenanthrene degradation by S. yanoikuyae in artificially contaminated Redi-earth-sand was examined.

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Phytoremediation of hydrocarbons in soil involves plants and their associated microorganisms. Differences in environmental conditions and restrictions on species importation mean that each country may need to identify indigenous plants to use for phytoremedation. Screening plants for hydrocarbon tolerance before screening for degradation ability may prove more economical than screening directly for degradation.

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