Nanomaterials (Basel)
September 2022
The request for extremely low-temperature and short-time sintering techniques has guided the development of alternative ceramic processing. Atmosphere-assisted FLASH sintering (AAFS) combines the direct use of electric power to packed powders with the engineering of operating atmosphere to allow low-temperature conduction. The AAFS of nanometric Potassium Sodium Niobate, K0.
View Article and Find Full Text PDFAlternative sintering technologies promise to overcome issues associated with conventional ceramic sintering such as high thermal budgets and CO footprint. The sintering process becomes even more relevant for alkali-based piezoelectric ceramics such as KNaNbO (KNN) typically fired above 1100 °C for several hours that induces secondary phase formation and, thereby, degrades their electrical characteristics. Here, an ability of KNN ceramics to be of high performance is successfully demonstrated, using an electric field- and current-assisted Flash sintering technique at 900 °C only.
View Article and Find Full Text PDFThe considerable decrease in temperature and time makes FLASH sintering a more sustainable alternative for materials processing. FLASH also becomes relevant if volatile elements are part of the material to be processed, as in alkali-based piezoelectrics like the promising lead-free KNaNbO (KNN). Due to the volatile nature of K and Na, KNN is difficult to process by conventional sintering.
View Article and Find Full Text PDFIf piezoelectric micro-devices based on KNaNbO (KNN) thin films are to achieve commercialization, it is critical to optimize the films' performance using low-cost scalable processing conditions. Here, sol-gel derived KNN thin films are deposited using 0.2 and 0.
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