Multiedge X-ray Absorption Spectroscopy Part II: XANES Analysis of Bridging and Terminal Chlorides in Hexachlorodipalladate(II) Complex.

X-ray absorption spectroscopy is a unique experimental technique that can provide ground state electronic structure information about transition metal complexes with unoccupied d-manifold. The quantitative treatments of pre-edge and rising-edge features have already been developed for the sulfur- and chlorine-ligand K-edge excitations. The complementarity of using multiple core excitation edges from hard, tender, and soft X-ray energy regions has been defined for the first paper of this series.