Nacre-like block lattice metamaterials with targeted phononic band gap and mechanical properties.

The extraordinary quasi-static mechanical properties of nacre-like composite metamaterials, such as high specific strength, stiffness, and toughness, are due to the periodic arrangement of two distinct phases in a "brick and mortar" structure. It is also theorized that the hierarchical periodic structure of nacre structures can provide wider band gaps at different frequency scales. However, the function of hierarchy in the dynamic behavior of metamaterials is largely unknown, and most current investigations are focused on a single objective and specialized applications.

Qualifying the contribution of fiber diameter on the acrylate-based electrospun shape memory polymer nano/microfiber properties.

Fibrous shape memory polymers (SMPs) have received growing interest in various applications, especially in biomedical applications, which offer new structures at the microscopic level and the potential of enhanced shape deformation of SMPs. In this paper, we report on the development and investigation of the properties of acrylate-based shape memory polymer fibers, fabricated by electrospinning technology with the addition of polystyrene (PS). Fibers with different diameters are manufactured using four different PS solution concentrations (25, 30, 35, and 40 wt%) and three flow rates (1.

Ductile Shape-Memory Polymer Composite with Enhanced Shape Recovery Ability.

In recent years, shape-memory polymers (SMPs) have received extensive attention to be used as actuators in a broad range of applications such as medical and robotic devices. Their ability to recover large deformations and their capability to be stimulated remotely have made SMPs a superior choice among different smart materials in various applications. In this study, a ductile SMP composite with enhanced shape recovery ability is synthesized and characterized.

Strategies for simultaneous strengthening and toughening via nanoscopic intracrystalline defects in a biogenic ceramic.

While many organisms synthesize robust skeletal composites consisting of spatially discrete organic and mineral (ceramic) phases, the intrinsic mechanical properties of the mineral phases are poorly understood. Using the shell of the marine bivalve Atrina rigida as a model system, and through a combination of multiscale structural and mechanical characterization in conjunction with theoretical and computational modeling, we uncover the underlying mechanical roles of a ubiquitous structural motif in biogenic calcite, their nanoscopic intracrystalline defects. These nanoscopic defects not only suppress the soft yielding of pure calcite through the classical precipitation strengthening mechanism, but also enhance energy dissipation through controlled nano- and micro-fracture, where the defects' size, geometry, orientation, and distribution facilitate and guide crack initialization and propagation.

Interaction of high-intensity focused ultrasound with polymers at the atomistic scale.

Experiments show that high-intensity focused ultrasound (HIFU) is a promising stimulus with multiple superior and unique capabilities to induce localized heating and achieve temporal and spatial thermal effects in the polymers, noninvasively. When polymers are subjected to HIFU, they heat up differently compared to the case they are subjected to heat sources directly; however, the origins of this difference are still entirely unknown. We hypothesize that the difference in the macroscale response of polymers subjected to HIFU strongly depends on the polymer chains, composition, and structure, i.

Bioinspired design of flexible armor based on chiton scales.

Man-made armors often rely on rigid structures for mechanical protection, which typically results in a trade-off with flexibility and maneuverability. Chitons, a group of marine mollusks, evolved scaled armors that address similar challenges. Many chiton species possess hundreds of small, mineralized scales arrayed on the soft girdle that surrounds their overlapping shell plates.

Multiscale mechanics of the lateral pressure effect on enhancing the load transfer between polymer coated CNTs.

While individual carbon nanotubes (CNTs) are known as one of the strongest fibers ever known, even the strongest fabricated macroscale CNT yarns and fibers are still significantly weaker than individual nanotubes. The loss in mechanical properties is mainly because the deformation mechanism of CNT fibers is highly governed by the weak shear strength corresponding to sliding of nanotubes on each other. Adding polymer coating to the bundles, and twisting the CNT yarns to enhance the intertube interactions are both efficient methods to improve the mechanical properties of macroscale yarns.

Defect-Tolerant Bioinspired Hierarchical Composites: Simulation and Experiment.

Defect tolerance, the capacity of a material to maintain strength even under the presence of cracks or flaws, is one of the essential demands in the design of composite materials, as manufacturing induced defects, or those generated during operation, can lead to catastrophic failure and dramatically reduce the mechanical performance. In this paper, we combine computational modeling and advanced multimaterial 3D printing to examine the mechanics of several different classes of defect-tolerant bioinspired hierarchical composites, built from two base materials with contrasting mechanical properties (stiff and soft). We find that in contrast to the brittle base constituents of the composites, the existence of a hierarchical architecture leads to superior defect-tolerant properties.

Mesoscale mechanics of twisting carbon nanotube yarns.

Fabricating continuous macroscopic carbon nanotube (CNT) yarns with mechanical properties close to individual CNTs remains a major challenge. Spinning CNT fibers and ribbons for enhancing the weak interactions between the nanotubes is a simple and efficient method for fabricating high-strength and tough continuous yarns. Here we investigate the mesoscale mechanics of twisting CNT yarns using full atomistic and coarse grained molecular dynamics simulations, considering concurrent mechanisms at multiple length-scales.

Tensile strength of carbyne chains in varied chemical environments and structural lengths.

Carbyne and carbyne-based low-dimensional structures are promising for several applications including ultra-compact circuits and purification devices. Designing any applied carbyne-based structure requires a fundamental understanding of the mechanical strength of carbyne chains with different lengths at different temperatures and operating chemical environment. Here we use molecular dynamics simulations to investigate the strength of carbyne chains with different lengths at different temperatures.