Triboelectric charge transfer is complex and depends on contact properties such as material composition and contact area, as well as environmental factors including humidity, temperature, and air pressure. Saturation surface charge density on particles is inversely dependent on particle size and the number of nearby particles. Here we show that electrical breakdown of air is the primary cause of triboelectric charge saturation on single and multiple electrically insulating particles, which explains the inverse dependence of surface charge density on particle size and number of particles.
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