Boosting the energy and power densities of electrochemical energy storage (EES) devices to broaden their practicality is of great significance and emergently desirable. Recently, the EES cells with an anode-free concept have been announced to realize those targets. Herein, 20 μm of a zincophilic layer prepared by blending ZIF-8 and sodium alginate (SA) is uniformly coated on Cu foil (Z8-SA@Cu) as an alternative anode for anode-less zinc-ion hybrid supercapacitors (ALZHSCs).
View Article and Find Full Text PDFBenefiting from the additional active sites for sodium-ion (Na) adsorption and porous architecture for electrolyte accessibility, nitrogen-doped porous carbon has been considered the alternative anode material for Na-storage applications. In this study, nitrogen-doped and zinc-confined microporous carbon (-MPC) powders are successfully prepared by thermally pyrolyzing the polyhedral ZIF-8 nanoparticles under an argon atmosphere. Following the electrochemical measurements, the -MPC not only delivers good reversible capacity (423 mAh/g at 0.
View Article and Find Full Text PDFHierarchical porous activated carbon (HPAC) materials with fascinating porous features are favored for their function as active materials for supercapacitors. However, achieving high mass-loading of the HPAC electrodes remains challenging. Inspired by the concepts of carbon/carbon (C/C) composites and hydrogels, a novel hydrogel-derived HPAC (H-HPAC) encapsulated H-HPAC (H@H) composite material was successfully synthesized in this study.
View Article and Find Full Text PDF