Preservation of the donor-acceptor character of a carbazole-phenalenone dyad upon adsorption on Pt(111).

Donor-acceptor molecules are a subject of great attention due to their immense potential in molecular electronics and photovoltaics. Despite numerous extensive studies demonstrating their functionality in solution, the donor-acceptor character is usually lost upon adsorption on a conducting substrate. Here the concept of breaking the conjugation between the donor and acceptor unit by insertion of a bridge is used.