Introduction: Continental hydrothermal systems (CHSs) are geochemically complex, and they support microbial communities that vary across substrates. However, our understanding of these variations across the complete range of substrates in CHS is limited because many previous studies have focused predominantly on aqueous settings.
Methods: Here we used metagenomes in the context of their environmental geochemistry to investigate the ecology of different substrates (i.
Hydrogen sulfide is a toxic gas but also established as a naturally occurring gaseous signaling molecule in humans, playing key physiological roles with particular involvement in lung disease including COVID-19. Thiosulfate is the conventional biomarker of hydrogen sulfide and is excreted in human urine at low micromolar levels. Thiosulfate is amenable to detection by the element-selective inductively coupled plasma tandem mass spectrometry (ICPMS/MS), but sulfur speciation in human samples at trace levels is challenging due to the high complexity of human sulfur metabolome and the utility of this detector under such settings has not been demonstrated.
View Article and Find Full Text PDFAlmost 140 years of industrial exploitation have severely degraded the environment of Bagnoli Coroglio (BC), the westernmost neighborhood of the city of Naples (Italy). In this peculiar area, however, geogenic processes overlap with the impact of human activities, making it difficult to distinguish between anthropogenic and geogenic pollution sources. This is particularly true for Arsenic, the concentration of which in the marine sediments largely exceeds the tolerable level for human health and the background value for local pyroclastics.
View Article and Find Full Text PDFIn the last decades, investigating geochemistry of sea sediments has been challenging in the eastern sector of Pozzuoli Bay, source of the metal(loid)s has been a matter of debate and the proposed origin of potentially toxic elements (PTEs) has been occasionally inconsistent. In this study, compositional data analysis (CoDA) was used because the results are independent of the measurement unit, the selected subgroup of elements and the order of chemicals in the dataset. The robust variant of principal component analysis (PCA) indicated that Hg, Cd, Cu, Pb and Zn were positively correlated with mud and organic matter in the sediments deposited in front of the former industrial site.
View Article and Find Full Text PDFBagnoli Coroglio is an urban district of the City of Naples (South Italy), which fronts the Tyrrhenian Sea for nearly 3 km. It is part of the Campi Flegrei caldera, one of the most explosive volcanic areas in Europe. The need for redeveloping the site after the intense industrial activities of the twentieth century has prompted a remarkable research effort to investigate the pollution's degree, nature, and extent at both the land and seafloor.
View Article and Find Full Text PDFThe coronavirus (COVID-19) pandemic was particularly invasive in Italy during the period between March and late April 2020, then decreased in both the number of infections and in the seriousness of the illness throughout the summer of 2020. In this work, we measure the severity of the disease by the ratio of Intensive Care Units (ICU) spaces occupied by COVID-19 patients and the number of Active Cases (AC) each month from April to October 2020. We also use the ratio of the number of Deaths (D) to the number of Active Cases.
View Article and Find Full Text PDFWe statistically investigate the Coronavirus Disease 19 (COVID-19) pandemic, which became particularly invasive in Italy in March 2020. We show that the high apparent lethality or case fatality ratio (CFR) observed in Italy, as compared with other countries, is likely biased by a strong underestimation of the number of infection cases. To give a more realistic estimate of the lethality of COVID-19, we use the actual (March 2020) estimates of the infection fatality ratio (IFR) of the pandemic based on the minimum observed CFR and analyze data obtained from the Diamond Princess cruise ship, a good representation of a "laboratory" case-study from an isolated system in which all the people have been tested.
View Article and Find Full Text PDFMonitoring volcanic phenomena is a key question, for both volcanological research and for civil protection purposes. This is particularly true in densely populated volcanic areas, like the Campi Flegrei caldera, which includes part of the large city of Naples (Italy). Borehole monitoring of volcanoes is the most promising way to improve classical methods of surface monitoring, although not commonly applied yet.
View Article and Find Full Text PDFWe applied the Eulerian code DISGAS (DISpersion of GAS) to investigate the dispersion of the hydrogen sulfide (HS) from 32 geothermal power plants (out of 35 active) belonging to the geothermal districts of Larderello, Travale-Radicondoli and Monte Amiata, in Tuscany (Italy). An updated geographic database, for use in a GIS environment, was realized in order to process input data required by the code and to handle the outputs. The results suggest that HS plumes emitted from geothermal power plants are mainly concentrated around the stacks of emission (HS concentration up to 1100μg/m) and rapidly dilute along the dominant local wind direction.
View Article and Find Full Text PDFWe report on a continuous-measurement campaign carried out in Vulcano (Aeolian islands, Sicily), devoted to the simultaneous monitoring of CO2 and H2O concentrations. The measurements were performed with an absorption spectrometer based on a semiconductor laser source emitting around a 2-microm wavelength. The emitted radiation was selectively absorbed by two molecular ro-vibrational transitions specific of the investigated species.
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