Laser texturing seems to be a promising technique for reducing bacterial adhesion on titanium implant surfaces. This work aims to demonstrate the possibility of obtaining a functionally orientated surface of titanium implant elements with a specific architecture with specific bacteriological and photocatalytic properties. Femtosecond laser-generated surface structures, such as laser-induced periodic surface structures (LIPSS, wrinkles), grooves, and spikes on titanium, have been characterised by XRD, Raman spectroscopy, and scanning electron microscopy (SEM).
View Article and Find Full Text PDFBinary AsSe alloys from the border of a glass-forming region (65 < < 70) subjected to nanomilling in dry and dry-wet modes are characterized by the XRPD, micro-Raman scattering (micro-RS) and revised positron annihilation lifetime (PAL) methods complemented by a disproportionality analysis using the quantum-chemical cluster modeling approach. These alloys are examined with respect to tetra-arsenic biselenide AsSe stoichiometry, realized in glassy g-AsSe, glassy-crystalline g/c-AsSe and glassy-crystalline g/c-AsSe. From the XRPD results, the number of rhombohedral As and cubic arsenolite AsO phases in As-Se alloys increases after nanomilling, especially in the wet mode realized in a PVP water solution.
View Article and Find Full Text PDFPlant-derived polyphenols are bioactive compounds with potential health-promoting properties including antioxidant, anti-inflammatory, and anticancer activity. However, their beneficial effects and biomedical applications may be limited due to their low bioavailability. In the present study, we have considered a microencapsulation-based drug delivery system to investigate the anticancer effects of polyphenol-rich (apigenin, caffeic acid, and luteolin) fractions, extracted from a cereal crop pearl millet (), using three phenotypically different cellular models of breast cancer in vitro, namely triple negative HCC1806, ER-positive HCC1428, and HER2-positive AU565 cells.
View Article and Find Full Text PDFPhotocatalytic degradation is a promising method for removing persistent organic pollutants from water because of its low cost (see solar-driven photocatalysis), high mineralisation of pollutants, and low environmental impact. Photocatalysts based on transition metal dichalcogenides (TMDs) have recently attracting high scientific interest due to their unique electrical, mechanical, and optical properties. A MoS photocatalyst of the layered structure was managed to photodegrade methylene blue (MB) under visible light irradiation.
View Article and Find Full Text PDFThe anticancer potential of quercetin (Q), a plant-derived flavonoid, and underlining molecular mechanisms are widely documented in cellular models in vitro. However, biomedical applications of Q are limited due to its low bioavailability and hydrophilicity. In the present study, the electrospinning approach was used to obtain polylactide (PLA) and PLA and polyethylene oxide (PEO)-based micro- and nanofibers containing Q, namely PLA/Q and PLA/PEO/Q, respectively, in a form of non-woven fabrics.
View Article and Find Full Text PDFBackground: Advanced Oxidation Processes (AOPs) are the water treatment techniques that are commonly used forthe decomposition of the non-biodegradable organic pollutants. However, some pollutants are electron deficient and thus resistant to attack by reactive oxygen species (e.g.
View Article and Find Full Text PDFWe demonstrate strain-balanced InAs/AlSb type-II superlattices (T2SL) grown on GaSb substrates employing two kinds of interfaces (IFs): AlAs-like IF and InSb-like IF. The structures are obtained by molecular beam epitaxy (MBE) for effective strain management, simplified growth scheme, improved material crystalline quality, and improved surface quality. The minimal strain T2SL versus GaSb substrate can be achieved by a special shutters sequence during MBE growth that leads to the formation of both interfaces.
View Article and Find Full Text PDFMultipurpose FeO@APTES-Ag heterostructures for mutual heat generation, SERS probing, and antimicrobial activity were fabricated using a three-step process. Silver metallic particles were precipitated on a thin silica shell that served as an interlayer with FeO nanocubes. The structural properties were studied by means of the powder X-ray diffraction technique, and selected area electron diffraction.
View Article and Find Full Text PDFPurpose: In this study, we hypothesize that exposure of adipose tissue-mesenchymal stem cells (AT-MSCs) to electromagnetic field (EMF) may impact adipose stem cells' micromolecular structure (analyzed using Fourier transform infrared spectroscopy [FTIR]).
Materials And Methods: The AT-MSCs were exposed to continuous vertically applied sinusoidal EMF with a frequency of 50 Hz and a flux density of 1.5 mT for 24, 48, and 72 h.
Early detection of the most common pediatric neoplasm, B-cell precursor lymphoblastic leukemia (BCP-ALL), is challenging and requires invasive bone marrow biopsies. The purpose of this study was to establish new biomarkers for early screening to detect pediatric leukemia. In this small cohort study, Fourier transform infrared (FTIR) spectra were obtained from blood sera of 10 patients with BCP-ALL and were compared with the control samples from 10 children with some conditions other than neoplasm.
View Article and Find Full Text PDFDevelopment of artificial enzymes, including nanozymes as an alternative for non-stable and expensive natural enzymes, is a booming field of modern Biosensorics and Biofuel Technology. In this study, we describe fabrication and characterization of sensitive biosensors for the detection of ethanol and glucose based on new micro/nanocomposite electrodes with peroxidase-like activity (nanozyme) coupled with microbial oxidases: alcohol oxidase (AOX) and glucose oxidase (GOX). The nanozyme was synthesized by modification of carbon microfibers (CF) by hemin (H) and gold (Au) nanoparticles.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
April 2020
In this study, we describe the fabrication of sensitive biosensor for the detection of phenolic substrates using laccase immobilized onto two types of microporous carbon fibers (CFs). The main characteristics of microporous CFs used for preparation of biosensors are given. Two CFs were characterized by different specific surface area, CFA (<1 m·g) and CFB (1448 m·g), but with comparable size of the micropores estimated by positron annihilation lifetime spectroscopy.
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