Electrochemical route outperforms chemical struvite precipitation in mitigating heavy metal contamination.

Electrochemically mediated struvite precipitation (EMSP) offers a robust, chemical-free process towards phosphate and ammonium reclamation from nutrients-rich wastewater, i.e., swine wastewater.

Basket anode filled with CaCO particles: A membrane-free electrochemical system for boosting phosphate recovery and product purity.

Phosphorus (P) is often regarded as the primary stimulant for eutrophication, while its importance as a crucial life element is also well acknowledged. Given its future scarcity, P recycling from waste streams is suggested and practiced. Electrochemically mediated precipitation (EMP) is a robust and chemical-free process for P removal and recovery, yet it requires further developments.

Removal of small elemental sulfur particles by polysulfide formation in a sulfidic reactor.

For over 30 years, biological gas desulfurization under halo-alkaline conditions has been studied and optimized. This technology is currently applied in already 270 commercial installations worldwide. Sulfur particle separation, however, remains a challenge; a fraction of sulfur particles is often too small for liquid-solid separation with conventional separation technology.

Electrochemically mediated precipitation of phosphate minerals for phosphorus removal and recovery: Progress and perspective.

Phosphorus (P) is an essential element for the growth and reproduction of organisms. Unfortunately, the natural P cycle has been broken by the overexploitation of P ores and the associated discharge of P into water bodies, which may trigger the eutrophication of water bodies in the short term and possible P shortage soon. Consequently, technologies emerged to recover P from wastewater to mitigate pollution and exploit secondary P resources.

Effect of sulfide on morphology and particle size of biologically produced elemental sulfur from industrial desulfurization reactors.

We investigated the effect of polysulfide formation on properties of biologically produced elemental sulfur (S) crystals, which are produced during biological desulfurization (BD) of gas. The recent addition of an anoxic-sulfidic reactor (AnSuR) to the BD process resulted in agglomerated particles with better settleability for S separation. In the AnSuR, polysulfides are formed by the reaction of bisulfide (HS) with S and are subsequently oxidized to S in a gas-lift reactor.

Novel Agglomeration Strategy for Elemental Sulfur Produced during Biological Gas Desulfurization.

This article presents a novel crystal agglomeration strategy for elemental sulfur (S) produced during biological desulfurization (BD). A key element is the nucleophilic dissolution of S by sulfide (HS) to polysulfides (S ), which was enhanced by a sulfide-rich, anoxic reactor. This study demonstrates that with enhanced S formation, crystal agglomerates are formed with a uniform size (14.

Electrochemical recovery of phosphorus from wastewater using tubular stainless-steel cathode for a scalable long-term operation.

Phosphorus (P) is an irreplaceable element, playing a vital role in living organisms, yet has limited earth reserves. The possibility of P recovery from wastewaters by electrochemically-induced calcium phosphate precipitation (ECaPP) was demonstrated previously. The current study presents a novel scalable prototype consisting of a column-shaped electrochemical reactor, a tubular stainless-steel cathode, and a Pt coated Ti anode.

Electrochemical Recovery of Phosphorus from Acidic Cheese Wastewater: Feasibility, Quality of Products, and Comparison with Chemical Precipitation.

The recovery of phosphorus (P) from high-strength acidic waste streams with high salinity and organic loads is challenging. Here, we addressed this challenge with a recently developed electrochemical approach and compared it with the chemical precipitation method via NaOH dosing. The electrochemical process recovers nearly 90% of P (∼820 mg/L) from cheese wastewater in 48 h at 300 mA with an energy consumption of 64.

Electrochemical removal of phosphate in the presence of calcium at low current density: Precipitation or adsorption？.

Phosphorus removal and recovery from waste streams are crucial to prevent eutrophication and sustain fertilizer production. As has been shown in our previous papers, electrochemical treatment has the potential to achieve this goal. However, the adoption of electrochemical approach is limited by its high energy consumption.

Electrochemically mediated calcium phosphate precipitation from phosphonates: Implications on phosphorus recovery from non-orthophosphate.

Phosphonates are an important type of phosphorus-containing compounds and have possible eutrophication potential. Therefore, the removal of phosphonates from waste streams is as important as orthophosphate. Herein, we achieved simultaneously removal and recovery of phosphorus from nitrilotris (methylene phosphonic acid) (NTMP) using an electrochemical cell.

Recovery of calcium phosphate granules from black water using a hybrid upflow anaerobic sludge bed and gas-lift reactor.

Adding calcium during anaerobic digestion of vacuum collected black water (BW) in an up-flow anaerobic sludge bed (UASB) reactor increased the retention of total phosphorus (P) in the reactor from 51% to 87%. However, the insufficient mixing in the reactor caused cementation and relatively high content of organics in the recovered calcium phosphate (CaP) granules, limiting the P recovery. In this study, the UASB reactor was mixed with an internal gas-lift (UASB-GL) to prevent cementation and to enhance the P content in CaP granules.

Calcium Carbonate Packed Electrochemical Precipitation Column: New Concept of Phosphate Removal and Recovery.

Phosphorus (P) is a vital micronutrient element for all life forms. Typically, P can be extracted from phosphate rock. Unfortunately, the phosphate rock is a nonrenewable resource with a limited reserve on the earth.

Influence of Cell Configuration and Long-Term Operation on Electrochemical Phosphorus Recovery from Domestic Wastewater.

Phosphorus (P) is an important, scarce, and irreplaceable element, and therefore its recovery and recycling are essential for the sustainability of the modern world. We previously demonstrated the possibility of P recovery by electrochemically induced calcium phosphate precipitation. In this Article, we further investigated the influence of cell configuration and long-term operation on the removal of P and coremoved calcium (Ca), magnesium (Mg), and inorganic carbon.

Bulk pH and Carbon Source Are Key Factors for Calcium Phosphate Granulation.

Recovery of calcium phosphate granules (CaP granules) from high-strength wastewater is an opportunity to reduce the natural phosphorus (P) scarcity, geographic imbalances of P reserves, and eutrophication. Formation of CaP granules was previously observed in an upflow anaerobic sludge bed (UASB) reactor treating source separated black water and is enhanced by Ca addition. However, the required operating conditions and influent composition for CaP granulation are still unknown.

The Effect of Bioinduced Increased pH on the Enrichment of Calcium Phosphate in Granules during Anaerobic Treatment of Black Water.

Simultaneous recovery of calcium phosphate granules (CaP granules) and methane in anaerobic treatment of source separated black water (BW) has been previously demonstrated. The exact mechanism behind the accumulation of calcium phosphate (Ca (PO) ) in CaP granules during black water treatment was investigated in this study by examination of the interface between the outer anaerobic biofilm and the core of CaP granules. A key factor in this process is the pH profile in CaP granules, which increases from the edge (7.

Is There a Precipitation Sequence in Municipal Wastewater Induced by Electrolysis?

Electrochemical wastewater treatment can induce calcium phosphate precipitation on the cathode surface. This provides a simple yet efficient way for extracting phosphorus from municipal wastewater without dosing chemicals. However, the precipitation of amorphous calcium phosphate (ACP) is accompanied by the precipitation of calcite (CaCO) and brucite (Mg(OH)).

Interaction of calcium, phosphorus and natural organic matter in electrochemical recovery of phosphate.

To address the issues of eutrophication and the potential risk of phosphorus (P) shortage, it is essential to remove and recover P from P-containing streams to close this nutrient cycle. Electrochemical induced calcium phosphate (CaP) precipitation was shown to be an efficient method for P recovery. However, the influence of natural organic matter (NOM) is not known for this treatment.

Calcium addition to increase the production of phosphate granules in anaerobic treatment of black water.

Simultaneous recovery of calcium phosphate granules (CaP granules) and methane from vacuum collected black water (BW), using an upflow anaerobic sludge blanket (UASB) reactor was previously investigated. It was calculated that only 2% of the total phosphorus (P) fed was present as CaP granules whereas 51% of the P accumulated dispersed in the reactor, limiting the applicability of this process for recovery of phosphate. This study proposes adding calcium to increase the P accumulation in the reactor and the production of CaP granules.

Electrochemical Induced Calcium Phosphate Precipitation: Importance of Local pH.

Phosphorus (P) is an essential nutrient for living organisms and cannot be replaced or substituted. In this paper, we present a simple yet efficient membrane free electrochemical system for P removal and recovery as calcium phosphate (CaP). This method relies on in situ formation of hydroxide ions by electro mediated water reduction at a titanium cathode surface.

Calcium phosphate granulation in anaerobic treatment of black water: a new approach to phosphorus recovery.

Recovery of phosphorus from wastewater as calcium phosphate could diminish the need for mining of scarce phosphate rock resources. This study introduces a novel approach to phosphorus recovery by precipitation of calcium phosphate granules in anaerobic treatment of black water. The granules formed in the Upflow Anaerobic Sludge Blanket (UASB) reactor at lab- and demonstration-scale were analyzed for chemical composition and mineralogy by Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES), Electron microprobe (EMP), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and micro X-ray Diffraction (XRD).

Microbiological selenate to selenite conversion for selenium removal.

Removal of the toxic selenium compounds selenite and selenate from waste water before discharge is becoming increasingly imperative in industrialized countries. Bacteria can reduce selenate to selenite, but also further to elemental selenium, selenide or organic selenium. In this paper, we aim to exclusively bio-reduce selenate to selenite in an open high-rate bioreactor.

Processing of arsenopyritic gold concentrates by partial bio-oxidation followed by bioreduction.

Gold is commonly liberated from sulfide minerals by chemical and biological oxidation. Although these technologies are successful, they are costly and produce acidic waste streams. Removal of mineral-sulfur to overcome the mineralogical barrier could also be done by bioreduction, producing hydrogen sulfide (H(2)S).