A critical review on metal-based catalysts used in the pyrolysis of lignocellulosic biomass materials.

This review discusses the technical aspects of improving the efficiency of the pyrolysis of lignocellulosic materials to increase the yield of the main products, which are bio-oil, biochar, and syngas. The latest aspects of catalyst development in the biomass pyrolysis process are presented focusing on the various catalyst structures, the physical and chemical performance of the catalysts, and the mode of the catalytic reaction. In bio-oil upgrading, atmospheric catalytic cracking is shown to be more economical than catalytic hydrotreating.