Publications by authors named "Reinhard Basse"
Organometallics
August 2021
Article Synopsis
- The study revisits an overlooked manganese sandwich complex that has 18 valence electrons, first discovered about 50 years ago by Fischer and Pauson, showcasing its unique properties.
- Advanced photochemical methods were developed to quickly synthesize the original complex and its functionalized variations with various substituents.
- Comprehensive analyses using various spectroscopic techniques and quantum chemical calculations reveal unique electrochemical behaviors and bonding characteristics that differentiate these tromancenium salts from similar complex salts of cobalt and early transition metals.
