J Phys Chem C Nanomater Interfaces
April 2024
Concentrated and thick oil-in-water nanoemulsions have been observed to become more transparent with increasing oil volume fraction. This study demonstrates rigorously experimentally and numerically that such unusual behavior is due to dependent scattering including not only far-field but also near-field effects. Indeed, when the droplet concentration is sufficiently large, their interparticle distance becomes small compared to the wavelength of light and scattering by a given droplet may be affected by the proximity of others.
View Article and Find Full Text PDFAltering wavelength via fluorescent particles is used in various applications. The solution of the broadband radiative transfer equation (RTE) for absorbing and anisotropically scattering a fluorescent medium is presented in this study considering fluorescent cascade, along with a Monte-Carlo-method-based solution of the equation. The path-length-based Monte Carlo method, the dual-stage method, and its modified version, the multi-stage method, which are used for solving the RTE in a fluorescent medium for biomedical and lighting applications, are not capable of accurately solving the broadband RTE with fluorescent cascade.
View Article and Find Full Text PDFWe propose a simple structure for passive sky radiative cooling made of a surface-textured layer of silica on a silver substrate. Using electromagnetic simulations, we show that the optical properties of such structures are near-ideal, due to the large reflectivity of silver in the solar spectrum and the large emissivity of silica in the infrared. Surface texturation is key to obtain near-unity emissivity in the infrared.
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