Publications by authors named "Reetam Kaushik"
Synthesis and characterization of self-assembled inorganic-organic hybrid arsenotungstates.
Acta Crystallogr C Struct Chem
December 2018
A series of 12 inorganic-organic hybrid 4f-substituted arsenotungstates decorated with 3d-based complexes along with acetate bridging, viz. {[Cu(HO)(1,10-phen)(μ-CHCOO)][Ln(HO)(μ-CHCOO)(α-AsWO)]} (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu), have been synthesized. These compounds were isolated using a one-pot synthetic strategy with copper, lanthanoid, trilacunary arsenotungstate and 1,10-phenanthroline as precursors.
View Article and Find Full Text PDFSynthesis and characterization of carbonate-encapsulated ytterbium- and yttrium-containing polyoxotungstates.
Acta Crystallogr C Struct Chem
November 2018
Article Synopsis
- A novel yttrium-containing arsenotungstate(III) polyanion has been synthesized using mild conditions, forming a solid crystalline material from a Y salt and sodium trilacunary arsenotungstate in sodium acetate.
- The polyanion, characterized by several analytical techniques, features a unique sandwich structure with carbonate encapsulation, where yttrium and tungsten ions are interlinked by acetate and sodium ions.
- Additionally, two new germanotungstates(IV) were created, which lack lone-pair heteroatoms but still exhibit a similar structure, with lanthanide ions facilitating higher-dimensional connections and hydrophilic pores present within the arrangement.