Caring for Indigenous Data to Evaluate the Benefits of Indigenous Environmental Programs.

Advances in open data, big data and data linkage allow us to analyse more data and on a larger scale than ever before. However, this brings with it the challenge of ensuring that Indigenous data sets are used in a way that protects Indigenous rights to that data and maximises benefits for Indigenous peoples. The CARE principles for Indigenous data governance-Collective Benefit, Authority to Control, Responsibility and Ethics-were developed to protect Indigenous data sovereignty, but there are few examples of how to translate these principles into practice.

Experimental and Theoretical Investigations of Infrared Multiple Photon Dissociation Spectra of Aspartic Acid Complexes with Zn and Cd.

Complexes of aspartic acid (Asp) cationized with Zn: Zn(Asp-H), Zn(Asp-H)(ACN) where ACN = acetonitrile, and Zn(Asp-H)(Asp); as well as with Cd, CdCl(Asp), were examined by infrared multiple photon dissociation (IRMPD) action spectroscopy using light generated from a free electron laser. A series of low-energy conformers for each complex was found using quantum chemical calculations to identify the structures formed experimentally. The main binding motif observed for the heavy-metal complex, CdCl(Asp)[N,CO,CO], is a charge-solvated, tridentate structure, where the metal center binds to the backbone amino group and carbonyl oxygens of the backbone and side-chain carboxylic acids.

Binding energies of hydrated cobalt(ii) by collision-induced dissociation and theoretical studies: evidence for a new critical size.

The experimental sequential bond energies for loss of water from Co(HO) complexes, x = 5-11, are determined by threshold collision-induced dissociation (TCID) using a guided ion beam tandem mass spectrometer with a thermal electrospray ionization source. Kinetic energy dependent TCID cross sections are analyzed to yield 0 K thresholds for sequential loss of neutral water molecules. The thresholds are converted from 0 to 298 K values to give hydration enthalpies and free energies.

Binding energies of hydrated cobalt hydroxide ion complexes: A guided ion beam and theoretical investigation.

The sequential bond energies of CoOH(HO) complexes, where x = 1-4, are measured by threshold collision-induced dissociation using a guided ion beam tandem mass spectrometer. The primary dissociation pathway for all reactants consists of loss of a single water molecule. This is followed by the sequential loss of additional water molecules at higher collision energies for the x = 2-4 complexes, whereas the x = 1 reactant loses the OH ligand competitively with the HO ligand.

Correction: Structural characterization of gas-phase cysteine and cysteine methyl ester complexes with zinc and cadmium dications by infrared multiple photon dissociation spectroscopy.

Correction for 'Structural characterization of gas-phase cysteine and cysteine methyl ester complexes with zinc and cadmium dications by infrared multiple photon dissociation spectroscopy' by Rebecca A. Coates et al., Phys.

Correction: Zn and Cd cationized serine complexes: infrared multiple photon dissociation spectroscopy and density functional theory investigations.

Correction for 'Zn and Cd cationized serine complexes: infrared multiple photon dissociation spectroscopy and density functional theory investigations' by Rebecca A. Coates et al., Phys.

Thermochemical Investigations of Hydrated Nickel Dication Complexes by Threshold Collision-Induced Dissociation and Theory.

The experimental bond energies of Ni(HO) complexes, where x = 4-11, are determined by threshold collision-induced dissociation using a guided ion beam tandem mass spectrometer with an electrospray ionization source. The electrospray ionization source produces a distribution of Ni(HO) complexes, where an in-source fragmentation technique is employed to access the x = 4-6 complexes and control the population of excited isomers. The kinetic energy-dependent cross sections are modeled to yield 0 K bond energies for sequential loss of neutral water molecules, which are converted to 298 K binding energies.

Four-Stage Audit Demonstrating Increased Uptake of HIV Testing in Acute Neurology Admissions Using Staged Practical Interventions.

Background: UK National Guidelines (UKNG) advise HIV testing in clinically indicated neurological presentations. We audited the impact of our practical strategies to increase uptake of HIV testing at a regional acute neurology admissions unit.

Methods: We audited HIV testing in 4 periods over 2 years: before we designed a UKNG-based "HIV testing in Neurology" protocol ("pre-protocol"); after dissemination of the protocol alone ("post-protocol"); post-protocol dissemination combined with both a tailored departmental admissions clerking proforma to prompt for HIV testing & consenting, and regular focussed tutorials to doctors on HIV testing in neurological patients ("post-proforma"); and finally one year after the post-proforma period ("+1 year").

Patient satisfaction with radioiodine treatment and telephone follow-up for the management of thyrotoxicosis.

Background And Objective: Patient satisfaction is of paramount importance when delivering a patient-centered service. Our hospital has been a center for the use of radioiodine to treat thyrotoxicosis for several years, but we began carrying out patient satisfaction surveys and implementing changes after 2008. The aim of the project reported here was to assess patient satisfaction with our radioiodine treatment and telephone follow-up service, and to compare results with our previous surveys.

Structural characterization of gas-phase cysteine and cysteine methyl ester complexes with zinc and cadmium dications by infrared multiple photon dissociation spectroscopy.

Structural characterization of gas-phase ions of cysteine (Cys) and cysteine methyl ester (CysOMe) complexed to zinc and cadmium is investigated by infrared multiple photon dissociation (IRMPD) action spectroscopy using a free electron laser in combination with density functional theory calculations. IRMPD spectra are measured for [Zn(Cys-H)](+), [Cd(Cys-H)](+), [Zn(CysOMe-H)](+), [Cd(CysOMe-H)](+) and CdCl(+)(CysOMe) and are accompanied by quantum mechanical calculations of the predicted linear absorption spectra at the B3LYP/6-311+G(d,p) (Zn(2+) complexes) and B3LYP/def2TZVP levels (Cd(2+) complexes). On the basis of these experiments and calculations, the conformation that best reproduces the IRMPD spectra for the complexes of the deprotonated amino acids, [M(Cys-H)](+) and [M(CysOMe-H)](+), is a charge-solvated (CS) tridentate structure where the metal dication binds to the amine and carbonyl groups of the amino acid backbone and the deprotonated sulfur atom of the side chain, [N,CO,S(-)].