Publications by authors named "Raul A Procaccini"

Three-dimensional (3D) porous anodes used in urine-powered bio-electrochemical applications usually lead to the growth of electro-active bacteria on the outer electrode surface, due to limited microbial access to the internal structure and lack of permeation of culture medium through the entire porous architecture. In this study, we propose the use of 3D monolithic TiO porous electrodes with controlled laminar structures as microbial anodes for urine-fed bio-electrochemical systems. The interlaminar distance was tuned to modulate the anode surface areas and, thus, the volumetric current densities.

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In this study, we prepared TiO porous electrodes with continuous layered structures characterized by different layer-to-layer distance (from 2 to 10 μm) but the same total void fraction (88-90%), to modulate the electrodes' permeability and the volumetric electrochemical surface area (from 90 to 840 cm cm). These platforms were evaluated as anodes in the electro-oxidation (EO) of bentazon in a three-electrode cell under galvanostatic conditions, operated both in traditional batch (TB) or batch recycle flow-through (BRFT) modes. The performance was significantly enhanced when the liquid was recirculated through the lamellar structure of the electrodes.

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Development of new functional coatings in the field of health care, as antibacterial applications, deals with a straight control of the diffusive properties that rules the releasing of the active component. In this work, the development of a silver-rich nanocomposite thin coating, loaded with organically modified clay nanoparticles, is presented. The synthesis process included an environment-friendly silanization process of clay nanoparticles (Laponite® S482) with (3-glycidoxypropyl)trimethoxysilane (GPTMS) and the further hydrolytic condensation with tetraethoxysilane (TEOS).

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