Catharanthus roseus-mediated CuAlO nanocomposites for evaluation of killing kinetics.

The present article portrayed on the killing kinetic of human pathogenic bacteria using bioinspired mesoporous CuAlO nanocomposites (NCs). The NCs was fabricated using leaf extract of medicinal plant Catharanthus roseus (CR) as a green reducer and stabilizer. As bio-fabricated material was calcined at 800 °C and characterized by several analytical techniques like X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Ultraviolet-Visible Diffuse Reflectance Spectroscopy (UV-DRS), Energy Dispersive X-Ray Spectroscopy (EDS), X-Ray Photoelectron Spectroscopy (XPS), Raman, Brunauer-Emmett-Teller (BET), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM) to authenticate its structure, phase, chemical bonding, chemical state, size and morphology behaviors.

Bioinspired graphene-based metal oxide nanocomposites for photocatalytic and electrochemical performances: an updated review.

Considering the rapidly increasing population, the development of new resources, skills, and devices that can provide safe potable water and clean energy remains one of the vital research topics for the scientific community. Owing to this, scientific community discovered such material for tackle this issue of environment benign, the new materials with graphene functionalized derivatives show significant advantages for application in multifunctional catalysis and energy storage systems. Herein, we highlight the recent methods reported for the preparation of graphene-based materials by focusing on the following aspects: (i) transformation of graphite/graphite oxide into graphene/graphene oxide exfoliation and reduction; (ii) bioinspired fabrication or modification of graphene with various metal oxides and its applications in photocatalysis and storage systems.

Biocompatibility assessment of chemically modified GONRs with hemoglobin and histopathological studies for its toxicity evaluation.

Transition metal-Schiff base complexes are found to be important for biomedical applications but have demerits of being homogeneous complexes, thus their synthesis on the surface of graphene oxide nanoribbons (GONRs), materials of specific interest, can be beneficial for preparing advanced graphene-based materials for biomedical applications. Of foremost importance is their safety and biocompatibility with biological systems. In this study, a transition metal-Schiff base complex has been synthesized on the surface of a GONR (Ni-S-GNR) using 3-aminopropyltriethoxysilane and pyridine-2-carbaldehyde and complexing nickel.

Electrochemical water splitting by a bidirectional electrocatalyst.

The presence of efficient energy storage and conversion technologies is essential for the future energy infrastructure. Here, we describe crafting a heterostructure composed of a suitably interlinked CeO and polycrystalline BiO dopant prepared on a reduced graphene oxide (Ce_BiO@rGO) surface. This material exhibits exceptional electrocatalytic hydrogen and oxygen evolution reaction in alkaline water (pH∼14.

Biomedical,clinical and environmental applications of platinum-based nanohybrids: An updated review.

Platinum nanoparticles (Pt NPs) have numerous applications in various sectors, including pharmacology, nanomedicine, cancer therapy, radiotherapy, biotechnology and environment mitigation like removal of toxic metals from wastewater, photocatalytic degradation of toxic compounds, adsorption, and water splitting. The multifaceted applications of Pt NPs because of their ultra-fine structures, large surface area, tuned porosity, coordination-binding, and excellent physiochemical properties. The various types of nanohybrids (NHs) of Pt NPs can be fabricated by doping with different metal/metal oxide/polymer-based materials.

Preparation of mesoporous ThO nanoparticles: Influence of calcination on morphology and visible-light-driven photocatalytic degradation of indigo carmine and methylene blue.

The present article reports the synthesis of thoria nanoparticles (ThO NPs) via sol-gel process and examines the effect of calcination temperature of ThO on the morphology and photocatalytic degradation of indigo carmine (IC) and methylene blue (MB) under visible-light. As-synthesized white crystals of ThO were subjected to calcination at different temperatures, viz. 700 °C (TH-700), 800 °C (TH-800), and 900 °C (TH-900).

Effect of Cu Doping on ZnO Nanoparticles as a Photocatalyst for the Removal of Organic Wastewater.

Environmental problems with chemical and biological water pollution have become a major concern for society. Providing people with safe and affordable water is a grand challenge of the 21st century. The study investigates the photocatalytic degradation capabilities of hydrothermally prepared pure and Cu-doped ZnO nanoparticles (NPs) for the elimination of dye pollutants.

Biosynthesized δ-BiO Nanoparticles from Flower Extract for Photocatalytic Dye Degradation and Molecular Docking.

Bioinspired delta-bismuth oxide nanoparticles (δ-BiO NPs) have been synthesized using a greener reducing agent and surfactant co-precipitation method. The originality of this work is the use of flower extract for the first time for the fabrication of NPs, which were further calcined at 800 °C to obtain δ-BiO NPs. Physicochemical studies such as FTIR spectroscopy and XPS confirmed the formation of BiO NPs, whereas XRD and Raman verified the formation of the cubic delta (δ) phase of BiO NPs.

Green Synthesized Nanomaterials for Safe Technology in Sustainable Agriculture.

Nanotechnology is a new emerging cutting-edge technology in the 21st century and has applications in medical, cosmetics, electronics, energy, food, agriculture, and many sectors. Nanomaterials (NMs) are the main component of nanotechnology. NMs prepared by chemical routes are very hazardous and not safe for life.

Bioinspired NiO Nanospheres: Exploring Toxicity Using Bm-17 and Liver Cells, DNA Degradation, Docking, and Proposed Vacuolization Mechanism.

The present work demonstrated a novel -mediated green fabrication of nickel oxide nanoparticles (NiO NPs) to explore toxicity in Bm-17 and liver cells. As-fabricated bioinspired NiO NPs were characterized by several analytical techniques. X-ray diffraction (XRD) revealed a crystalline face-centered-cubic structure.

Biogenic Synthesis of Metal/Metal Oxide Nanostructured Materials.

Nanotechnology is an emerging outlet of nanoscience in which the atoms are encompassed in nanoscale dimensions and become more receptive compared with their distinctive counterparts. Recently, the utilization of synthetic designs and physicochemical approaches has received special attention; nevertheless, the generation of noxious impressions on the eco-system has raised serious concerns of the scientific community worldwide. Presently, environment-friendly green synthesis routes are promising venues for the arrangement of Metal/Metal Oxide (M/MO) nanostructured materials by using plants and their corresponding alliances.

A Survey on Analytical Methods for the Characterization of Green Synthesized Nanomaterials.

Nowadays, nanotechnologies are well established and the uses of a great variety of nanomaterials show exponential growth. The development of green synthesis procedures experienced a great development thanks to the contribution of researchers of diverse origins. The versatility of green chemistry allows producing a wide range of organic and inorganic nanomaterials with numerous promising applications.

Bioinspired Reduced Graphene Oxide Based Nanohybrids for Photocatalysis and Antibacterial Applications.

Ultra-thin graphene has been receiving significance in the diverse sections of material science, owing to its exceptional physicochemical and thermo-mechanical characteristics. Currently, the fabrication of high-grade graphene in an economical target and green procedures area is a massive concern. Among the diverse techniques, chemical-mediated fabrication is believed to be the finest process since it is simple, scalable, and of low-cost; however, it involves noxious or hazardous chemical reducers for producing functional graphene-based Nanocomposites (NCs).

Mesoporous Octahedron-Shaped Tricobalt Tetroxide Nanoparticles for Photocatalytic Degradation of Toxic Dyes.

The present article reports a facile approach to fabrication of mesoporous octahedron-shaped tricobalt tetroxide nanoparticles (CoO NPs) with a very narrow size distribution for eco-friendly remediation of toxic dyes. CoO NPs were fabricated by a solgel process using cobalt chloride hexahydrate (CoCl·6HO) and monosodium succinate (CHONa) as a chelating/structure-directing agent and sodium dodecyl sulfate as a surfactant. Moreover, the phase structure, elemental composition, and thermal and morphological facets of CoO NPs were investigated using XRD, FT-IR, EDS, Raman, XPS, TGA, SEM, and TEM techniques.

Sulfamic acid promoted one-pot multicomponent reaction: a facile synthesis of 4-oxo-tetrahydroindoles under ball milling conditions.

We report an efficient and facile one-pot synthesis of 4-oxo-tetrahydroindoles using sulfamic acid under ball milling conditions. The present protocol for preparation of biologically important 4-oxo-tetrahydroindoles offers several advantages such as mild reaction conditions, improved selectivity and higher isolated yields. Moreover, solvent-free reaction conditions and the use of ball milling make the present protocol environmentally friendly in nature.

Metal/Metal Oxide Nanoparticles: Toxicity, Applications, and Future Prospects.

The ever-growing resistance of pathogens to antibiotics and crop disease due to pest has triggered severe health concerns in recent years. Consequently, there is a need of powerful and protective materials for the eradication of diseases. Metal/metal oxide nanoparticles (M/MO NPs) are powerful agents due to their therapeutic effects in microbial infections.

Mesoporous PbO nanoparticle-catalyzed synthesis of arylbenzodioxy xanthenedione scaffolds under solvent-free conditions in a ball mill.

A protocol for the efficient synthesis of arylbenzodioxy xanthenedione scaffolds was developed a one-pot multi-component reaction of aromatic aldehydes, 2-hydroxy-1,4-naphthoquinone, and 3,4-methylenedioxy phenol using mesoporous PbO nanoparticles (NPs) as a catalyst under ball milling conditions. The synthesis protocol offers outstanding advantages, including short reaction time (60 min), excellent yields of the products (92-97%), solvent-free conditions, use of mild and reusable PbO NPs as a catalyst, simple purification of the products by recrystallization, and finally, the use of a green process of dry ball milling.

Phytosynthesis of nearly monodisperse CuO nanospheres using Phyllanthus reticulatus/Conyza bonariensis and its antioxidant/antibacterial assays.

In the present article we have developed an eco-friendly, phytosynthetic, cost-effective and straightforward method for the synthesis of nearly monodisperse CuO nanospheres (NSP) using leaf extracts of medicinal plants Phyllanthus reticulatus (PR) and Conyza bonariensis (CB) as novel green reducing agents. Copper nitrate (Cu (NO)) was used as a precursor. The stoichiometric ratio of both leaf extracts (PR/CB) and Cu(NO) was standardized for the synthesis of NSP.