Tunable Photocatalytic Activity of CoFe Prussian Blue Analogue Modified SrTiO Core-Shell Structures for Solar-Driven Water Oxidation.

This study presents a pioneering semiconductor-catalyst core-shell architecture designed to enhance photocatalytic water oxidation activity significantly. This innovative assembly involves the in situ deposition of CoFe Prussian blue analogue (PBA) particles onto SrTiO (STO) and blue SrTiO (bSTO) nanocubes, effectively establishing a robust p-n junction, as demonstrated by Mott-Schottky analysis. Of notable significance, the STO/PB core-shell catalyst displayed remarkable photocatalytic performance, achieving an oxygen evolution rate of 129.