Methylene Blue, a cationic dye, was retained from aqueous solutions using a novel biosorbent made of poly(vinyl alcohol) reticulated with tricarboxi-cellulose produced via TEMPO oxidation (OxC25). The study of the Methylene Blue biosorption process was performed with an emphasis on operational parameters that may have an impact on it (such as biosorbent concentration, pH of the aqueous media, and temperature). The current study focused on three areas: (i) the physic-chemical characterization of the biosorbent (scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX)); (ii) biosorption data modeling to determine the quantitative characteristic parameters employing three equilibrium isotherms (Langmuir, Freundlich, and Dubinin-Radushkevich-DR); and (iii) the study of temperature influence.
View Article and Find Full Text PDFCeO/ZnO-based photocatalytic materials were synthesized by the sol-gel method in order to establish heterojunctions that increase the degradation efficiency of some types of antibiotics by preventing the recombination of electron-hole pairs. The synthesized materials were analysed by XRD, SEM, EDAX, FTIR, and UV-Vis. After several tests, the optimal concentration of the catalyst was determined to be 0.
View Article and Find Full Text PDFUsing various techniques, natural polymers can be successfully used as a matrix to immobilize a residual microbial biomass in a form that is easy to handle, namely biosorbents, and which is capable of retaining chemical species from polluted aqueous media. The biosorption process of reactive Brilliant Red HE-3B dye on a new type of biosorbent, based on a residual microbial biomass of immobilized in sodium alginate, was studied using mathematical modeling of experimental data obtained under certain conditions. Different methods, such as computer-assisted statistical analysis, were applied, considering all independent and dependent variables involved in the reactive dye biosorption process.
View Article and Find Full Text PDFThe use of a biosorbent based on residual biomass from brewing industry () immobilized in a natural biopolymer (sodium alginate) was investigated for Methylene Blue removal from aqueous medium. , immobilized by a simple entrapment technique and by microencapsulation in alginate was characterized using SEM, EDAX, pH and the biosorption behavior toward organic pollutant, such as cationic dye. The biosorption experiments were studied by assessing, in a first stage, the influence of the most important operational physical parameters on the efficiency of the biosorbent: the initial concentration of the dye, the contact time between phases, the temperature, the dye solution pH, the biosorbent granule size, and the amount of biosorbent.
View Article and Find Full Text PDFNatural polymers can themselves be efficient as materials with biosorptive properties but can also be used to transform microbial biomass into an easy-to-handle form, respectively, into biosorbents, through immobilization. The article aims to study biosorbents based on residual microbial biomass ( yeast, separated after the brewing process by centrifugation and dried at 80 °C) immobilized in sodium alginate. The biosorptive properties of this type of biosorbent (spherical particles 2 and 4 mm in diameter) were studied for removal of reactive dye Brilliant Red HE-3B (with concentration in range of 16.
View Article and Find Full Text PDFNatural polymers have proven to be extremely interesting matrices for the immobilization of microbial biomasses, via various mechanisms, in order to bring them into a form easier to handle-the form of composites. This article aimed to study composites based on a residual microbial biomass immobilized in sodium alginate via an encapsulation technique as materials with adsorbent properties. Thus, this study focused on the residual biomass resulting from beer production ( yeast, separated after the biosynthesis process by centrifugation and dried at 80 °C)-an important source of valuable compounds, used either as a raw material or for transformation into final products with added value.
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