Unlocking the Electrocatalytic Behavior of CuMnS Nanoflake-Anchored rGO for the Oxygen Evolution Reaction in an Alkaline Medium.

A catalyst of the oxygen evolution reaction (OER) that is viable, affordable, and active for effective water-splitting applications is critical. A variety of electrocatalysts have been discovered to replace noble metal-based catalysts. Of these, transition metal-based sulfides are essential for incorporating carbonaceous materials to improve electrical conductivity, resulting in better electrocatalytic performance.

Green synthesis of multifunctional carbon quantum dots: An approach in cancer theranostics.

Carbon quantum dots (CQDs) have gained significant growing attention in the recent past due to their peculiar characteristics including smaller size, high surface area, photoluminescence, chemical stability, facile synthesis and functionalization possibilities. They are carbon nanostructures having less than 10 nm size with fluorescent properties. In recent years, the scientific community is curiously adopting biomass precursors for the preparation of CQDs over the chemical compounds.

A sustainable green synthesis of functionalized biocompatible carbon quantum dots from Aloe barbadensis Miller and its multifunctional applications.

Herein, we demonstrated a sustainable green approach for the preparation of fluorescent biocompatible carbon quantum dots by microwave-assisted reflux synthesis from Aloe barbadensis Miller (Aloe vera) extract. The Transmission Electron Microscopic images reveal that the as-prepared CQDs are spherical with less than 5 nm in size. The CQDs are amorphous, showed an excitation-independent behaviour, emitted blue fluorescence and have a fluorescence quantum yield of 31%.

Microwave-assisted green synthesis of fluorescent carbon quantum dots from Mexican Mint extract for Fe detection and bio-imaging applications.

Biomass-derived carbon quantum dots have drawn special interest owing to their admirable photostability, biocompatibility, fluorescence, high solubility, sensitivity and environmentally friendly properties. In the present work, the Carbon Quantum Dots (CQDs) was synthesized from the Plectranthus amboinicus (Mexican Mint) leaves via the microwave-assisted reflux method. The strong absorption peaks observed from UV-vis spectra at 291 and 330 nm corresponds to the π-π* and n-π* transitions, respectively, reveal the formation of CQDs.

Polyol assisted formaldehyde reduction of bi-metallic Pt-Pd supported agro-waste derived carbon spheres as an efficient electrocatalyst for formic acid and ethylene glycol oxidation.

This report explains, (i) the preparation of carbon spheres (CS) from agro-waste through hydrothermal carbonization (HTC) followed by high temperature carbonization, (ii) the decoration of bi-metallic Pt-Pd nanoparticles (Pt-Pd NPs) with different compositions (Pt/C, PtPd/C, PtPd/C and PtPd/C, Pd/C) on the carbon by ethylene glycol solvated polyol assisted formaldehyde reduction method and (iii) subsequently used as the electrocatalyst for formic acid (FA) and ethylene glycol (EG) electro-oxidation. The structural and morphological properties of the electrocatalysts were studied using advanced physicochemical characterization techniques. The obtained results well evidence the homogeneous dispersion of Pt-Pd NPs on the surface of the carbon.

Preparation of starch-based porous carbon electrode and biopolymer electrolyte for all solid-state electric double layer capacitor.

An ever-increasing demand for energy coupled with environmental pollution associated with conventional energy production continues to drive the search for alternative renewable energy storage solutions. In this regard, a high surface area (1841 m g), hierarchically porous (∼1.18 cm g) and self-inherited nitrogen (2.

Facile hydrothermal synthesis of carbon-coated cobalt ferrite spherical nanoparticles as a potential negative electrode for flexible supercapattery.

Battery type electrodes would replace the currently available pseudocapacitive electrodes by the cause of high energy density and long discharge time. In this regard, battery type carbon coated CoFeO spherical nanoparticles is prepared by the facile hydrothermal method and tested as the possible negative electrode for supercapattery applications. The phase purity, electronic states of elements, and the presence of carbon is inferred through various sophisticated techniques.

Biomass-derived porous carbon modified glass fiber separator as polysulfide reservoir for Li-S batteries.

Biomass-derived porous carbon has been considered as a promising sulfur host material for lithium-sulfur batteries because of its high conductive nature and large porosity. The present study explored biomass-derived porous carbon as polysulfide reservoir to modify the surface of glass fiber (GF) separator. Two different carbons were prepared from Oak Tree fruit shells by carbonization with and without KOH activation.

Facile hydrothermal synthesis and characterization of CoGeO/r-GO@C ternary nanocomposite as negative electrode for Li-ion batteries.

Ternary nanocomposite of CoGeO/r-GO@C is synthesized by single step hydrothermal method followed by calcination. The XRD analysis reveals the formation of cubic structured CoGeO and their corresponding functional groups identified through Raman analysis. The TEM analysis assures that uniform distribution of CoGeO nanoparticles on the r-GO layers.

Surfactant-free hydrothermal synthesis of hierarchically structured spherical CuBi2O4 as negative electrodes for Li-ion hybrid capacitors.

Hierarchically structured spherical CuBi2O4 particles were prepared using a facile hydrothermal method without using a surfactant over various hydrothermal reaction periods. The prepared CuBi2O4 samples were examined via X-ray diffraction (XRD), which confirmed the formation of a tetragonal crystal structure. The morphological features were analyzed using field emission scanning electron microscopy (FESEM), which elucidated the construction of the hierarchical microspherical CuBi2O4 particles.

Hydrothermal synthesis and electrochemical performances of 1.7 V NiMoO₄⋅xH₂O||FeMoO₄ aqueous hybrid supercapacitor.

One-dimensional (1D) NiMoO4⋅xH2O nanorods and β-FeMoO4 microrods are successfully synthesized by simple hydrothermal method without using any organic solvents. X-ray diffraction (XRD) patterns reveal the single phase formation of nickel molybdate (NiMoO4⋅xH2O) and pure monoclinic phase of β-FeMoO4. The growth of one dimensional morphology of both the molybdates are identified from scanning and transmission electron microscopes (SEM and TEM).

The sonochemical synthesis and characterization of Cu(1-x)Ni(x)WO4 nanoparticles/nanorods and their application in electrocatalytic hydrogen evolution.

Cu(1-x)Ni(x)WO(4) (x = 0.0, 0.2, 0.