Publications by authors named "Ramadoss Manigandan"

Highly efficient interfacial contact between components in nanohybrids is a key to achieving great photocatalytic activity in photocatalysts and degradation of organic model pollutants under visible light irradiation. Herein, we report the synthesis of nano-assembly of graphene oxide, zinc oxide and cerium oxide (GO-ZnO@CeO) nanohybrids constructed by the hydrothermal method and subsequently annealed at 300 °C for 4 h. The unique graphene oxide sheets, which are anchored with semiconducting materials (ZnO and CeO nanoparticles), act with a significant role in realizing sufficient interfacial contact in the new GO-ZnO@CeO nanohybrids.

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The ease of production of materials and showing multiple applications are appealing in this modern era of advanced technology. This paper reports the synthesis of a pair of novel cobalt-iron chalcogenides [CoFeS and CoFeSe] with enhanced electro catalytic activities. These ternary metal chalcogenides were synthesized by a one-step template-free approach a hexamethyldisilazane (HMDS)-assisted synthetic method.

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The rational design and demonstration of a facile sequential template-mediated strategy to construct noble-metal-free efficient bifunctional electrocatalysts for efficient oxygen evolution reaction (OER) and electrocatalytic detection of hazardous environmental 4-nitrophenol (4-NP) have continued as a major challenging task. Herein, we construct a novel Ag@polymer/NiAl LDH (designated as APL) nanohybrid as an efficient bifunctional electrocatalyst by a simple hydrolysis method. The well-fabricated APL/GCE exhibited an extensive linear range from 0.

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Herein, a simple, highly efficient and stable MoS nanobox embedded graphitic-CN@TiO (g-CN@TiO) nanoarchitecture was synthesized by a facile solvothermal approach. The nano-hybrid photocatalyst was constructed by TiO nanoparticles anchored on the surface of g-CN nanosheets. Then highly crystalline three-dimensional porous MoS nanobox was homogeneously distributed on the g-CN@TiO surface.

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Rational design and highly efficient dual-functional catalyst are still difficult to develop for electrocatalytic oxygen evolution reaction and degradation of RhB dye pollutant. Herein, we report a highly efficient "bandgap matching and interfacial coupling" strategy to synthesize nano-assembled ultrathin layered MoS@NiFeO (MS@NiFeO) bifunctional catalyst constructed by the hydrothermal route and subsequently amine-hydrolysis. The OER performance of the prepared MS@NiFeO catalyst delivers a low overpotential of 290 mV at 10 mA/cm and Tafel slope is 69.

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It is urgent and significant to develop competent, inexpensive transition metal-based catalysts with multifunctional catalytic properties for wide applications. To meet this requirement, herein, for the first time, we present a novel bifunctional CoSnS@CNT hybrid via a simple one-pot surfactant-free hydrothermal method. The CoSnS@CNT hybrid has a unique three-dimensional (3D) porous nanoarchitecture, which is constructed by ultrathin CoSnS homogenously and compactly anchored on a highly conductive CNT skeleton.

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Although tungsten carbide (W2C) has long been reported as an excellent platinum-like catalyst, it is still a challenge to synthesize W2C as an electrocatalyst for a highly efficient hydrogen evolution reaction (HER) due to its high onset overpotential, inevitable aggregation, and lack of a scalable and controllable synthesis method. Herein, we synthesized W2C nanodot-decorated CNT networks (W2C@CNT-S) via a facile and scalable spray drying method followed by a carbonization process. It is demonstrated that this unique nanoarchitecture, constructed by ultrafine W2C nanodots homogeneously decorated on a three-dimensional and conductive CNT skeleton, leads to the exposure of abundant catalytic sites and promotes highly efficient electron transfer and ion diffusion during the HER process.

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Increasing resistance of pathogens and cancer cell line towards antibiotics and anticancer agents has caused serious health problems in the past decades. Due to these problems in recent years, researchers have tried to combine nanotechnology with material science to have intrinsic antimicrobial and anticancer activity. The metals and metal oxides were investigated with respect to their antimicrobial and anticancer effects towards bacteria and cancer cell line.

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A poly(methylene blue)-modified glassy carbon electrode (PMB/GCE) was fabricated by electropolymerisation of methylene blue on a GCE and further utilized to investigate the electrochemical determination of 4-nitrophenol (4-NP) by cyclic voltammetry (CV), differential pulse voltammetry and chronocoulometry. The morphology of the PMB on GCE was examined using a scanning electron microscope (SEM). An oxidation peak of 4-NP at the PMB modified electrode was observed at 0.

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