Pesticides vs. Biopesticides: From Pest Management to Toxicity and Impacts on the Environment and Human Health.

The environmental pollution that occurs in direct response to the widespread use of man-made/conventional pesticides results from many chemicals that require a long period of time, often decades, to degrade. The synthetic nature of pesticides also harms animals, beneficial insects, microorganisms, and plants, as well as humans. Fortunately, however, there are many natural pesticides, the so-called biopesticides, that are also effective against pests and more importantly, do not interfere with the well-being of ecosystems.

Intensification of the photodegradation efficiency of an emergent water pollutant through process conditions optimization by means of response surface methodology.

Heterogeneous photocatalysis has been increasingly investigated during the past years and has been recognized as a promising technique for clean and safe water purification. The current study exploits the advantage of this technique demonstrating that the removal of a biorefractory water pollutant named clofibric acid can be really improved by photocatalysis through a parametric comprehensive investigation and optimization study based on response surface methodology. Its novelty comes from the approach used to enhance the efficiency of the photocatalytic degradation of clofibric acid.

Medicinal Plant Growth in Heavy Metals Contaminated Soils: Responses to Metal Stress and Induced Risks to Human Health.

Accelerating heavy metal pollution is a hot issue due to a continuous growth in consumerism and increased activities in various global industries. Soil contamination with heavy metals has resulted in their incorporation into the human food web via plant components. Accumulation and amplification of heavy metals in human tissues through the consumption of medicinal plants can have hazardous health outcomes.

New Evidence of Model Crop L. in Soil Clean-Up: Comparison of Tolerance and Accumulation of Lead and Cadmium.

The potential of the model crop L. (rapeseed) for the phytoremediation of soils polluted with metals was investigated at laboratory scale. The first step consists in the evaluation of the seed germination and growth of the L.

Characterization of heavy metal toxicity in some plants and microorganisms-A preliminary approach for environmental bioremediation.

In situ bioremediation processes are important for control of pollution and clean-up of contaminated sites. The study and implementation of such processes can be designed through investigations on natural mechanisms of absorption, biotransformation, bioaccumulation and toxicity of pollutants in plants and microorganisms. Here, the phytotoxic effects of Cr(VI) and Cd(II) on seed germination and plant growth of Lepidium sativum have been examined at various concentrations (30-300 mg/L) in single ion solutions.

Modelling the behavior of pesticide residues in tomatoes and their associated long-term exposure risks.

This study is focused on the dissipation behavior of 7 fungicides and 5 insecticides applied in tomatoes after a third spraying at recommended and double doses by considering 6 kinetic models which allow estimating the pesticides half-lives (t). Except studying the pesticides dissipation, another scope of our manuscript was investigating the risk to human health after application of different pesticide treatments in tomatoes. The pesticides analysis in tomatoes at harvest showed that the residues were below the maximum residue level (MRL), with the exception of chlorotalonil (included in Group 2B - "Possibly carcinogenic to humans") and bifenthrin for recommended dose treatments, while for double dose treatments, the MRLs was exceeded for 7 pesticides, once again including chlorotalonil.

The role of Arthrobacter viscosus in the removal of Pb(II) from aqueous solutions.

The aim of this paper was to establish the optimum parameters for the biosorption of Pb(II) by dead and living Arthrobacter viscosus biomass from aqueous solution. It was found that at an initial pH of 4 and 26 °C, the dead biomass was able to remove 97% of 100 mg/L Pb(II), while the living biomass removed 96% of 100 mg/L Pb(II) at an initial pH of 6 and 28 ± 2 °C. The results were modeled using various kinetic and isotherm models so as to find out the mechanism of Pb(II) removal by A.

Rhizobacteria and plant symbiosis in heavy metal uptake and its implications for soil bioremediation.

Certain species of plants can benefit from synergistic effects with plant growth-promoting rhizobacteria (PGPR) that improve plant growth and metal accumulation, mitigating toxic effects on plants and increasing their tolerance to heavy metals. The application of PGPR as biofertilizers and atmospheric nitrogen fixators contributes considerably to the intensification of the phytoremediation process. In this paper, we have built a system consisting of rhizospheric Azotobacter microbial populations and Lepidium sativum plants, growing in solutions containing heavy metals in various concentrations.

Experimental analysis and mathematical prediction of Cd(II) removal by biosorption using support vector machines and genetic algorithms.

We investigated the bioremoval of Cd(II) in batch mode, using dead and living biomass of Trichoderma viride. Kinetic studies revealed three distinct stages of the biosorption process. The pseudo-second order model and the Langmuir model described well the kinetics and equilibrium of the biosorption process, with a determination coefficient, R(2)>0.