Long-wave infrared pulsed external-cavity QCL spectrometer using a hollow waveguide gas cell.

A spectrometer built using an external cavity pulsed quantum cascade laser is described. The spectrometer has a tuning range from 10 - 13 µm (1,000 - 769 cm) and is designed to target volatile organic compounds (VOCs) which often exhibit water-free molecular absorption within the region. The spectrometer utilizes a hollow silica waveguide gas cell which has an internal volume of a few millilitres, a fast response time (∼1 s), and is advantageous when only low sample volumes, similar to the cell volume, are available.

Automated Interlayer Wall Height Compensation for Wire Based Directed Energy Deposition Additive Manufacturing.

Part quality monitoring and control in wire-based directed energy deposition additive manufacturing (w-DEDAM) processes has been garnering continuous interest from both the academic and industrial sectors. However, maintaining a consistent layer height and ensuring that the wall height aligns closely with the design, as depicted in computer-aided design (CAD) models, pose significant challenges. These challenges arise due to the uncertainties associated with the manufacturing process and the working environment, particularly with extended processing times.

High sensitivity pressure measurement using optical fibre sensors mounted on a composite diaphragm.

A pressure sensor specified for aerodynamic applications and based on optical fibre strain sensors mounted on a circular glass fibre reinforced polymer membrane is presented. The use of two fibre optic strain sensing technologies is explored, the novel intrinsic fibre segment interferometry (FSI) approach and fibre Bragg gratings (FBGs), with the use of FSI shown to offer a pressure resolution that is 15 times larger than that achieved using an FBG. A number of design and fabrication issues are considered, including the position of the fibres relative to the neutral axis of the membrane and the influence of the membrane support structure on the thermal and pressure sensitivities of the sensor, with particular regards to pressure and temperature discrimination.

Polarization-sensitive transfer matrix modeling for displacement measuring interferometry.

The use of polarizing optics for both beam steering and phase measurement applications in displacement measuring interferometer designs is almost universal. Interferometer designs that employ polarizing optics in this manner are particularly sensitive to the effects of unwanted optical cavities that form within the optics due to polarization leakage and back reflections from material interfaces. Modeling techniques commonly employed in the design of such interferometers are poorly suited to the analysis of multiple passes through polarizing optics.

Instrumentation for quantitative analysis of volatile compounds emission at elevated temperatures. Part 1: Design and implementation.

A novel suite of instrumentation for the characterisation of materials held inside an air-tight tube furnace operated up to 250 °C has been developed. Real-time detection of released gases (volatile organic compounds (VOCs), CO, NO, NO, SO, CO and O) was achieved combining commercial off-the-shelf (COTS) gas sensors and sorbent tubes for further qualitative and semi-quantitative analysis by gas chromatography-mass spectrometry coupled to thermal desorption (TD-GC-MS). The test system was designed to provide a controlled flow (1000 cm min) of hydrocarbon free air through the furnace.

Instrumentation for quantitative analysis of volatile compounds emission at elevated temperatures. Part 2: Analysis of carbon fibre reinforced epoxy composite.

We have investigated the release of gases and volatile organic compounds (VOCs) from a carbon fibre reinforced epoxy composite matrix used in aircraft structural components. Analysis was performed at several temperatures both up to and above the recommended operating temperature (121 °C) for the material, to a maximum of 250 °C. Gas chromatography-mass spectrometry (GC-MS) combined with thermal desorption (TD-GC-MS) was used to identify and quantify VOCs, and in parallel real-time gas detection with commercial off-the-shelf (COTS) gas sensors.

2D Spatially-Resolved Depth-Section Microfluidic Flow Velocimetry Using Dual Beam OCT.

A dual beam optical coherence tomography (OCT) instrument has been developed for flow measurement that offers advantages over microscope derived imaging techniques. It requires only a single optical access port, allows simultaneous imaging of the microfluidic channel, does not require fluorescent seed particles, and can provide a millimetre-deep depth-section velocity profile (as opposed to horizontal-section). The dual beam instrument performs rapid re-sampling of particle positions, allowing measurement of faster flows.

Metre-per-second microfluidic flow velocimetry with dual beam optical coherence tomography.

A novel dual beam Optical Coherence Tomography (OCT) instrument has been developed for high velocity flow measurement, principally in microfluidics applications. The scanned dual beam approach creates a pair of image-frames separated by a small spatiotemporal offset. Metre-per-second flow measurement is achieved by rapid re-imaging by the second beam allowing for particle tracking between each image-frame of the pair.

Influence of aberrations on confocal-based remote refractive index measurements.

Confocal scanning combined with low-coherence interferometry is used to provide remote refractive index and thickness measurements of transparent materials. The influence of lens aberrations in the confocal measurement is assessed through ray-trace modeling of the axial point-spread functions generated using optical configurations comprised of paired aspherics and paired achromats. Off-axis parabolic mirrors are suggested as an alternative to lenses and are shown to exhibit much more symmetric profiles provided the system numerical aperture is not too high.

Performance and Analysis of Feature Tracking Approaches in Laser Speckle Instrumentation.

This paper investigates the application of feature tracking algorithms as an alternative data processing method for laser speckle instrumentation. The approach is capable of determining both the speckle pattern translation and rotation and can therefore be used to detect the in-plane rotation and translation of an object simultaneously. A performance assessment of widely used feature detection and matching algorithms from the computer vision field, for both translation and rotation measurements from laser speckle patterns, is presented.

Tapered Optical Fibre Sensors: Current Trends and Future Perspectives.

The development of reliable, affordable and efficient sensors is a key step in providing tools for efficient monitoring of critical environmental parameters. This review focuses on the use of tapered optical fibres as an environmental sensing platform. Tapered fibres allow access to the evanescent wave of the propagating mode, which can be exploited to facilitate chemical sensing by spectroscopic evaluation of the medium surrounding the optical fibre, by measurement of the refractive index of the medium, or by coupling to other waveguides formed of chemically sensitive materials.

Spectrometer-based refractive index and dispersion measurement using low-coherence interferometry with confocal scanning.

This paper describes a technique for measuring refractive index and thickness of transparent plates using a fibre-optic low-coherence interferometer. The interferometer is used to independently measure quantities related to the phase and group refractive indices, n and n, of the material under investigation. Additionally, the dispersion of the phase index dependent quantity is measured by taking advantage of the range of wavelengths available from a broadband source.

Sensitivity Enhancement in Low Cutoff Wavelength Long-Period Fiber Gratings by Cladding Diameter Reduction.

The diameter of long-period fiber gratings (LPFGs) fabricated in optical fibers with a low cutoff wavelength was be reduced by hydrofluoric acid etching, enhancing the sensitivity to refractive index by more than a factor of 3, to 2611 nm/refractive index unit in the range from 1.333 to 1.4278.

Passively-coupled, low-coherence interferometric duct profiling with an astigmatism-corrected conical mirror.

Duct-profiling in test samples up to 25 mm in diameter has been demonstrated using a passive, low-coherence probe head with a depth resolution of 7.8 μm, incorporating an optical-fibre-linked conical mirror addressed by a custom-built array of single-mode fibres. Zemax modelling, and experimental assessment of instrument performance, show that degradation of focus, resulting from astigmatism introduced by the conical mirror, is mitigated by the introduction of a novel lens element.

Volatile Organic Compounds Sensing Using Optical Fibre Long Period Grating with Mesoporous Nano-Scale Coating.

A long period grating (LPG) modified with a mesoporous film infused with a calixarene as a functional compound was employed for the detection of individual volatile organic compounds (VOCs) and their mixtures. The mesoporous film consisted of an inorganic part, SiO₂ nanoparticles (NPs), along with an organic moiety of poly(allylamine hydrochloride) polycation PAH, which was finally infused with the functional compound, p-sulphanato calix[4]arene (CA[4]) or p-sulphanato calix[8]arene (CA[8]). The LPG sensor was designed to operate at the phase matching turning point to provide the highest sensitivity.

Overwrite fabrication and tuning of long period gratings.

The central wavelengths of the resonance bands are critical aspect of the performance of long period gratings (LPGs) as sensors, particularly for devices designed to operate near the phase matching turning point (PMTP), where the sensitivity to measurements can vary rapidly. Generally, LPGs are characterized by their period, but the amplitude of the amplitude of the index modulation is also an important factor in determining the wavelengths of the resonance bands. Variations in fabrication between LPG sensors can increase or decrease the sensitivity of the LPG to strain, temperature or surrounding refractive index.

Low-volume, fast response-time hollow silica waveguide gas cells for mid-IR spectroscopy.

Hollow silica waveguides (HSWs) are used to produce long path length, low-volume gas cells, and are demonstrated with quantum cascade laser spectroscopy. Absorption measurements are made using the intrapulse technique, which allows measurements to be made across a single laser pulse. Simultaneous laser light and gas coupling is achieved through the modification of commercially available gas fittings with low dead volume.

Monitoring techniques for the manufacture of tapered optical fibers.

The use of a range of optical techniques to monitor the process of fabricating optical fiber tapers is investigated. Thermal imaging was used to optimize the alignment of the optical system; the transmission spectrum of the fiber was monitored to confirm that the tapers had the required optical properties and the strain induced in the fiber during tapering was monitored using in-line optical fiber Bragg gratings. Tapers were fabricated with diameters down to 5 μm and with waist lengths of 20 mm using single-mode SMF-28 fiber.

Noise analysis for CCD-based ultraviolet and visible spectrophotometry.

We present the results of a detailed analysis of the noise behavior of two CCD spectrometers in common use, an AvaSpec-3648 CCD UV spectrometer and an Ocean Optics S2000 Vis spectrometer. Light sources used include a deuterium UV/Vis lamp and UV and visible LEDs. Common noise phenomena include source fluctuation noise, photoresponse nonuniformity, dark current noise, fixed pattern noise, and read noise.

Range-resolved interferometric signal processing using sinusoidal optical frequency modulation.

A novel signal processing technique using sinusoidal optical frequency modulation of an inexpensive continuous-wave laser diode source is proposed that allows highly linear interferometric phase measurements in a simple, self-referencing setup. Here, the use of a smooth window function is key to suppress unwanted signal components in the demodulation process. Signals from several interferometers with unequal optical path differences can be multiplexed, and, in contrast to prior work, the optical path differences are continuously variable, greatly increasing the practicality of the scheme.

Objective speckle displacement: an extended theory for the small deformation of shaped objects.

This paper describes an extended and improved theory of the displacement of the objective speckle pattern resulting from displacement and/or deformation of a coherently illuminated diffuse object. Using the theory developed by Yamaguchi [Opt. Acta 28, 1359 (1981)], extended expressions are derived that include the influence of surface shape/gradients via the first order approximation of the shape as linear surface gradients.

Fabrication of fiber optic long period gratings operating at the phase matching turning point using an ultraviolet laser.

It is known that optical fiber long period gratings (LPGs) exhibit their highest sensitivity to environmental perturbation when the period is such that the phase matching condition is satisfied at its turning point. The reproducible fabrication of LPGs with parameters satisfying this condition requires high resolution control over the properties of the grating. The performance of an LPG fabrication system based on the point-by-point UV exposure approach is analyzed in this paper, and the control of factors influencing reproducibility, including period, duty cycle, and the environment in which the device is fabricated, is explored.

Frequency division multiplexing for interferometric planar Doppler velocimetry.

A new method of acquiring simultaneously the signal and reference channels used for interferometric planar Doppler velocimetry is proposed and demonstrated. The technique uses frequency division multiplexing (FDM) to facilitate the capture of the requisite images on a single camera, and is suitable for time-averaged flow measurements. Furthermore, the approach has the potential to be expanded to allow the multiplexing of additional measurement channels for multicomponent velocity measurement.

A long period grating-based chemical sensor insensitive to the influence of interfering parameters.

An optical fibre chemical sensor that is insensitive to interfering parameters including temperature and surrounding refractive index is described. The sensor is based upon a Mach-Zehnder interferometer formed by a pair of identical cascaded long period gratings (LPGs), with the entire device coated with a mesoporous coating of silica nanoparticles. A functional material is infused only into the coating over the section of optical fibre separating the LPGs.

Selective vancomycin detection using optical fibre long period gratings functionalised with molecularly imprinted polymer nanoparticles.

An optical fibre long period grating (LPG) sensor modified with molecularly imprinted polymer nanoparticles (nanoMIPs) for the specific detection of antibiotics is presented. The operation of the sensor is based on the measurement of changes in refractive index induced by the interaction of nanoMIPs deposited onto the cladding of the LPG with free vancomycin (VA). The binding of nanoMIPs to vancomycin was characterised by a binding constant of 4.