A ratiometric luminescence thermometer based on lanthanide encapsulated complexes.

Lanthanide-containing complexes have been widely developed as ratiometric luminescence thermometers, which are non-invasive, contactless and accurate. The synthesis of these Ln complexes generally requires high temperatures, multiple steps and other harsh conditions. Moreover, bimetallic lanthanide complexes, which have been reported to be better thermometers, are even more challenging to synthesize.

Controlled Noncovalent Synthesis of Secondary Supramolecular Polymers.

Dynamic supramolecular polymers, with their functional similarities to classical covalent polymers and their adaptive and self-repairing nature reminiscent of biological assemblies, have emerged as highly promising systems for the design of smart soft materials. Recent advancements in mechanistic investigations and novel synthetic strategies, such as living supramolecular polymerization, have significantly enhanced our ability to control the primary structure of these supramolecular polymers. However, realizing their full functional potential requires expanding their topological diversity in a manner akin to classical polymers as well as achieving precise molecular organization at higher hierarchical levels of self-assembly.

Secondary Nucleation-Triggered Physical Cross-Links and Tunable Stiffness in Seeded Supramolecular Hydrogels.

Mechanistic understanding and the control of molecular self-assembly at all hierarchical levels remain grand challenges in supramolecular chemistry. Functional realization of dynamic supramolecular materials especially requires programmed assembly at higher levels of molecular organization. Herein, we report an unprecedented molecular control on the fibrous network topology of supramolecular hydrogels and their resulting macroscopic properties by biasing assembly pathways of higher-order structures.

Energy transfer in FRET pairs in a supramolecular hydrogel template.

Fluorescence resonance energy transfer (FRET) in pairs of chromophores has mostly been achieved using covalently bound chromophores. In this study, we have demonstrated energy transfer in FRET pairs by taking advantage of the self-assembly of the chromophores on metal cholate hydrogel fibers.

Supramolecular Gelation of Europium and Calcium Cholates through the Nucleation-Elongation Growth Mechanism.

A detailed understanding of gelation mechanism can enable the properties of gels to be tuned for various applications, and may possibly help in understanding the aggregation of different biomolecules. We report a detailed study of the morphological and physio-chemical changes, dynamics (of a probe), and kinetics during the gelation of europium and calcium cholate hydrogels, leading to the development of a growth model. AFM images showed the transition of aggregated particles (100-150 nm) in the sol phase growing to a fibrous network in the gel through the entanglement of fibres, and not by dendritic growth (height analysis).

A Stimuli-Responsive Metallohydrogel Exhibiting Cyclohexane-Like Hydrophobicity.

Silver(I) forms a hydrogel in the presence of cholate with unusual properties, which are not observed with other cations. Polarity-sensitive probes have shown that the spherical aggregates observed in the gel have 'pockets' with hydrophobicity comparable to that of degassed cyclohexane. The gel exhibited thermo- and mechanoresponsive properties.