Hitting Reset on Sediment Toxicity: Sediment Homogenization Alters the Toxicity of Metal-Amended Sediments.

Laboratory testing of sediments frequently involves manipulation by amendment with contaminants and homogenization, which changes the physicochemical structure of sediments. These changes can influence the bioavailability of divalent metals, and field and mesocosm experiments have shown that laboratory-derived thresholds are often overly conservative. We assessed the mechanisms that lead to divergence between laboratory- and field-derived thresholds; specifically, we assessed the importance of slow equilibration to solid-phase ligands and vertical stratification.

Metal Oxides in Surface Sediment Control Nickel Bioavailability to Benthic Macroinvertebrates.

In aquatic ecosystems, the cycling and toxicity of nickel (Ni) are coupled to other elemental cycles that can limit its bioavailability. Current sediment risk assessment approaches consider acid-volatile sulfide (AVS) as the major binding phase for Ni, but have not yet incorporated ligands that are present in oxic sediments. Our study aimed to assess how metal oxides play a role in Ni bioavailability in surficial sediments exposed to effluent from two mine sites.