Applying 3D X-ray Microscopy to Model Coated Gasoline Particulate Filters under Practical Driving Conditions.

Recent progress in 3D X-ray microscopy allows the analysis of coated gasoline particulate filters on a detailed pore-scale level. However, derivable detailed three-dimensional models for filter simulation are not applicable under transient driving conditions of automotive aftertreatment systems due to their inherent complexity. Here, we present a novel concept to utilize highly resolved 3D X-ray microscopy scans and their quantitative analysis for a macroscopic model of coated gasoline particulate filters intended to be applied in a driving cycle.

Extended Model for Filtration in Gasoline Particulate Filters under Practical Driving Conditions.

In order to reliably predict the particle number filtration of gasoline particulate filters (GPF) under practical driving conditions, an extension to established filtration models is developed. For the validation of this approach and in order to close a gap of available measurement data at high space velocity in the literature, the particle-size-resolved fresh filtration efficiency of seven different cordierite filters is determined experimentally. Moreover, the experiments on a dynamic engine test bench focus on the impact of the pore-size distribution and the filter wall thickness under steady-state as well as transient, cold-start conditions.

Further Studies on How the Nature of Zeolite Cavities That Are Bounded by Small Pores Influences the Conversion of Methanol to Light Olefins.

A series of small-pore zeolites are synthesized and investigated as catalysts for the methanol-to-olefins (MTO) reaction. Small-pore zeolites SSZ-13, SSZ-16, SSZ-27, SSZ-28, SSZ-52, SSZ-98, SSZ-99, SSZ-104, SSZ-105 and an ITQ-3-type material are synthesized, and the results from their use as catalytic materials in the MTO reaction compared to those obtained from SAPO-34. The production of propane that tends to correlate with catalytic material lifetime (higher initial propane yields lead to shorter lifetimes) declines with increasing Si/Al (as has been observed previously for SSZ-13), and a larger cage dimension leads to higher propane yields at a fixed Si/Al.