An Asymmetric Coumarin-Anthracene Conjugate as Efficient Fullerene-Free Acceptor for Organic Solar Cells.

Asymmetric wide-band gap fullerene-free acceptors (FFAs) play a crucial role in organic solar cells (OSCs). Here, we designed and synthesized a simple asymmetric coumarin-anthracene conjugate named CA-CN with optical band gap of 2.1 eV in a single-step condensation reaction.

Impact of high energy photons on physical, structural and magnetic properties of MnZnFeNdO nanoparticles.

Ultrafine powders of Nd doped Mn-Zn ferrite powders with composition MnZnFeNdO (x = 0.04, 0.06, 0.

Effects of Halogenation on Cyclopentadithiophenevinylene-Based Acceptors with Excellent Responses in Binary Organic Solar Cells.

In recent years, non-fused non-fullerene acceptors (NFAs) have attracted increasing consideration due to several advantages, which include simple preparation, superior yield, and low cost. In the work reported here, we designed and synthesized three new NFAs with the same cyclopentadithiophenevinylene (CPDTV) trimer as the electron-donating unit and different terminal units (IC for , IC-4F for , and IC-4Cl for ). Both halogenated NFAs, i.

Impact of gadolinium doping into the frustrated antiferromagnetic lithium manganese oxide spinel.

Cubic spinel LiMnO (LMO) are promising electrode materials for advanced technological devices owing to their rich electrochemical properties. Here, a series of Gd-doped LiMnO were synthesized using a simple one-step sol-gel synthesis, and a systematized study on the effect of increasing Gd concentration on magnetic properties is conferred. The Raman and density functional theory (DFT) calculations of the synthesized materials were correlated with the magnetic properties; we observed a high coercivity value for the doped LMO compared to pristine LMO, which scales down from 0.

Microstructural tuning and band gap engineering of calcium hydroxides: a novel approach by pH variation.

Here we report a simple, inexpensive, energy benign, yet novel pH-driven chemical precipitation technique to achieve microstructural and band gap engineering of calcium hydroxide nanoparticles (CHNPs). The chemical precipitation route involved the use of 0.4-1.

Optical band gap enhancements of chemically synthesized α-Ni(OH) nanoparticles by a novel technique: Precipitator molarity variation.

Nickel hydroxide nanoparticles (NHNPs) are extremely important semiconducting materials for applications in energy storage and energy harvesting devices. This study uses a novel variation in molarity of the sodium hydroxide (NaOH) precipitator solution to enhance the direct optical band gap in the NHNPs chemically synthesized by using nickel nitrate hexahydrate (Ni(NO ) ·6H O) as the precursor. The simple, energy benign chemical precipitation route involved the usage of 1 M (Ni(NO ) ·6H O) solutions as the precursor and 0.

Modeling nonlinear high-pressure sensors based on degenerate four-wave mixing in photonic crystal fibers.

We propose a high-pressure sensing mechanism in solid-core silica photonic crystal fibers (PCF) that is based on the nonlinear optical process of degenerate four-wave mixing. A quite simple configuration for the pressure sensor is given and is theoretically investigated by obtaining signal gain spectra. We focus on the Stokes and anti-Stokes sidebands that are generated during propagation of the field along the PCF due to the interplay of dispersion and nonlinear optical effects.

Luminescence studies of binding affinity of vildagliptin with bovine serum albumin.

Vildagliptin (VDG)is a frontier drug for diabetes mellitus. It is prescribed both in the monotherapy as well as in an amalgamation with other antidiabetic drugs. Drug-serum protein binding is an essential parameter which influences ADME properties of the drug.

New Medium Bandgap Donor D-A -D-A Type Copolymers Based on Anthra[1,2-b: 4,3-b":6,7-c"'] Trithiophene-8,12-dione Groups for High-Efficient Non-Fullerene Polymer Solar Cells.

A new acceptor unit anthra[1,2-b: 4,3-b': 6,7-c'']trithiophene-8,12-dione (А3Т) (A2) is synthesized and used to design D-A -D-A medium bandgap donor copolymers with same thiophene (D) and A2 units but different A1, i.e., fluorinated benzothiadiazole (F-BTz) and benzothiadiazole (BTz) denoted as P130 and P131, respectively.

Fullerene/Non-fullerene Alloy for High-Performance All-Small-Molecule Organic Solar Cells.

Organic solar cells (OSCs) that contain small molecules only were prepared with as the donor, a narrow band gap non-fullerene acceptor , and a wide band gap PCBM. The OSCs based on optimized : (1:1.2) and :PCBM (1:1.

Reducing Energy Loss in Organic Solar Cells by Changing the Central Metal in Metalloporphyrins.

The effect of central donor core on the properties of A-π-D-π-A donors, where D is a porphyrin macrocycle, cyclopenta[2,1-b:3,4-b']dithiophene is the π bridge, and A is a dicyanorhodanine terminal unit, was investigated for the fabrication of the organic solar cells (OSCs), along [6,6]-phenyl-C71-butyric acid methyl ester (PC BM) as electron acceptor. A new molecule consisting of Ni-porphyrin central donor core (VC9) showed deep HOMO energy level and OSCs based on optimized VC9:PC BM realized overall power conversion efficiency (PCE) of 10.66 % [short-circuit current density (J )=15.

Edge plane pyrolytic graphite as a sensing surface for the determination of fluvoxamine in urine samples of obsessive-compulsive disorder patients.

There is an increasing demand for fast and sensitive determination of antidepressants in human body fluids because of the present scenario of rising depression cases at the global level. A simple and sensitive voltammetric method using edge plane pyrolytic graphite electrode (EPPGE) as a novel sensor is presented for the determination of antidepressant fluvoxamine in urine and blood plasma samples of obsessive-compulsive disorder (OCD) patients. EPPGE is delineated the first time for this determination.

Efficient Fullerene-Free Organic Solar Cells Using a Coumarin-Based Wide-Band-Gap Donor Material.

In recent years, tremendous growth has been seen for solution-processed bulk heterojunction solar cells (BHJSCs) using fullerene-free molecular acceptors. Herein, we report the synthesis, characterization of a coumarin-based organic semiconducting molecule C1, and its use in BHJSCs as an electron donor. The compound exhibited an absorption band at 472 nm in chloroform solution with an optical energy gap of 2.

Nano-scale depth-varying recrystallization of oblique Ar sputtered Si(111) layers.

Silicon, the workhorse of semiconductor industry, is being exploited for various functional applications in numerous fields of nanotechnology. In this paper, we report the fabrication of depth controllable amorphous silicon (a-Si) layers under 80 keV Ar ion sputtering at off-normal ion incidences of 30°, 40° and 50° and crystallization of these amorphous Si(111) layers under thermal annealing. We find that the irradiated samples were not fully amorphized even for the lowest oblique incidence of 30°.

Electrical transport properties of InAs nanowires synthesized by a solvothermal method.

Nanowires are widely considered to be key elements in future disruptive electronics and photonics. This paper presents the first detailed study of transport mechanisms in single-crystalline InAs nanowires synthesized by a cheap solvothermal wet chemical method. From detailed analyses of temperature-dependent current-voltage characteristics, it was observed that contacted nanowires operate in a linear transport regime at biases below a critical cross-over voltage.

Nanoscale structural defects in oblique Ar sputtered Si(111) surfaces.

The present endeavor investigates the controlled surface modifications and evolution of self-assembled nano-dimensional defects on oblique Ar sputtered Si(111) surfaces which are important substrates for surface reconstruction. The defect formation started at off-normal incidences of 50° and then deflates into defined defect zones with decrease in oblique incidence, depending strongly on angle of ion incidence. Interestingly, it is observed that mean size & height decreases while average density of these defects increases with decreasing oblique incidence.

Three-Year Outcomes of Biodegradable Polymer-Coated Ultra-Thin (60 µm) Sirolimus-Eluting Stents in Real-World Clinical Practice.

Introduction: Although drug-eluting stents (DES) have outclassed the use of bare metal stents, the safety and efficacy of DES at long-term follow-up has still been conflicting because of increased occurrence of late or very late restenosis and stent thrombosis after DES implantation. Hence, the present study was aimed to evaluate the 3-year safety and clinical performance of biodegradable polymer-coated ultra-thin (60 µm) sirolimus-eluting stent (SES) in real-world patients with coronary artery disease (CAD).

Materials And Methods: This was a physician-initiated, retrospective, single-centre, observational study that included 237 consecutive patients who had previously undergone implantation of only Supraflex SES (Sahajanand Medical Technologies Pvt Ltd, Surat, India) for the treatment of CAD.

Self-assembled nano-dots structures on Si(111) surfaces by oblique angle sputter-deposition.

Controlled surface modification and nano-dots structures over Si(111) surfaces have been produced by oblique angle sputter deposition of 80 keV Ar beam. Temporal parameters such as self-assemble, tunability of size and density of fabricated nano-dots exhibit distinct fluence dependence. Crystalline to amorphous (c/a) phase transition for sputter deposited Si(111) surfaces has been observed.

Enhanced room temperature ferromagnetism and green photoluminescence in Cu doped ZnO thin film synthesised by neutral beam sputtering.

The Cu (3 to 15 at%) is incorporated into ZnO thin film by atomic beam co-sputtering has been investigated for enhancement in room temperature ferromagnetism and green photo-luminance. These Cu-ZnO thin films examined with Raman spectroscopy, X-Ray Diffraction (XRD), UV-Visible spectroscopy, Hall measurement, magnetic force microscopy (MFM) and magnetic hysteresis. Raman spectroscopy, XRD confirms wurtzite structure and improvement in the crystallinity of ZnO upto 7% Cu.

Near-IR Absorbing D-A-D Zn-Porphyrin-Based Small-Molecule Donors for Organic Solar Cells with Low-Voltage Loss.

Two D-A-D small molecules with a DPP acceptor core and Zn-porphyrin donor with different electron-donating substituents, namely, 2,6-bis(dodecyloxy)phenyl and 5-hexylthieno[3,2- b]thiophen-2-yl at mesopositions, VC4 and VC5, were synthesized, and their optical and electrochemical properties were investigated. The results reveal that both molecules are suitable as donors for organic solar cells (OSCs) in which PCBM is employed as the acceptor. Overall power conversion efficiencies of 8.

Ni-Porphyrin-based small molecule for efficient organic solar cells (>9.0%) with a high open circuit voltage of over 1.0 V and low energy loss.

A new A-π-D-π-A small molecule with a Ni-porphyrin core (MV143) has been synthesized and employed as a donor, along with PC71BM, for the fabrication of solution-processed bulk heterojunction OSCs organic solar cells. The device exhibited an overall PCE of 9.14% (JSC = 13.

Corrole-BODIPY Dyad as Small-Molecule Donor for Bulk Heterojunction Solar Cells.

Dyes based on charge-transfer (CT) characteristics are attractive candidates for organic photovoltaics due to their intense and broad absorption window. In these molecular frameworks, electron-rich donors and electron-deficient acceptors are covalently linked to achieve an effective CT process. Corrole, a tetrapyrrolic congener of porphyrin, is an excellent example of an electron-rich molecule with a large molar extinction coefficient.