The advantage of secondary-phase induced carrier filtering on the thermoelectric properties has paved the way for developing cost-effective, highly efficient thermoelectric materials. Here, we report a very high thermoelectric figure-of-merit of skutterudite nanocomposites achieved by tailoring interface carrier filtering. The single-filled skutterudite nanocomposites are prepared by dispersing rare-earth oxides nanoparticles (YbO, SmO, LaO) in the skutterudite (DyCoNiSb) matrix.
View Article and Find Full Text PDFSpinel NiFeOnanoparticles have been synthesized via hydrothermal route usingflower extract (MIFE) as a green surfactant and reducing agent. X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy techniques have been used to determine the structure and morphology. The formation of single-phase, monodispersed NiFeOwith mixed morphology, the predominant shape being of equi-axed nanoparticles having an average particle size ≲45 nm, is observed.
View Article and Find Full Text PDFWe report a systematic investigation of the microstructure and thermoelectric properties of refractory element-filled nanostructured CoSb skutterudites. The refractory tantalum (Ta) metal-filled CoSb samples (Ta CoSb ( = 0, 0.4, 0.
View Article and Find Full Text PDFLiNiCoAlO (NCA) possessing a nano-/micro hierarchical architecture delivers a high specific capacity of 200 mAh/g with an upper cutoff voltage of 4.4 V. However, the structural reconstruction due to the irreversibility of the H2 ↔ H3 phase transition at higher voltage increases the initial irreversible capacity loss and charge-transfer impedance and reduces the performance at higher C-rates.
View Article and Find Full Text PDFHere, we report facile fabrication of Fe3O4-reduced graphene oxide (Fe3O4-RGO) composite by a novel approach, i.e., microwave assisted combustion synthesis of porous Fe3O4 particles followed by decoration of Fe3O4 by RGO.
View Article and Find Full Text PDF