Int J Biol Macromol
October 2021
A new adsorbent from chitosan and anionic silica was prepared by ionic interaction followed by sol-gel process. The obtained nanocomposite was characterized by different techniques: FTIR, XRD, SEM/EDX, TGA, and TEM. The results showed that silica precursor interacts with chitosan and deposits as regular spherical nanoparticles.
View Article and Find Full Text PDFAccording to the World Health Organization, nearly a billion people do not have incoming to pure drinking water and much of that water is contaminated with high levels of heavy elements. In this study, adsorption of lead ions has been studied by nanocomposites which prepared through acrylic acid grafting and amino-functionalized magnetized (FM-NPs) TEMPO-oxidized cellulose nanofiber (TEMPO-CNF). The amino-functionalized magnetite was acting as a crosslinked.
View Article and Find Full Text PDFCellulose nanocrystal (CNC) and ZnO/CuO nanostructure were successfully synthesized by acid hydrolysis and sol-chemical methods, respectively. For the first time, CNC was used as a host polymer for synthesis of CNC/ZnO/CuO through In-situ solution casting technique. Morphological and structural of CNC, ZnO/CuO and hybrid CNC/ZnO/CuO were investigated by TEM, SEM-EDX, FT-IR, XRD and XPS analyses.
View Article and Find Full Text PDFTEMPO oxidized cellulose nanofibers (T-CNF) were prepared from cellulose pulp which is extracted from bagasse. Soy protein hydrolysate (SPH) was grafted on T-CNF via amidation of carboxylic groups. Biomineralization was, then, assessed via calcium phosphates (CaP) precipitation in twice-simulated body fluid until formation of a new bioactive material.
View Article and Find Full Text PDFIn the current article di-aldehyde alginate (DAA) crosslinking gelatin (Ge) hydrogel was prepared and investigated for stabilizing silver nanoparticles. DAA/Ge decorated silver nanoparticles hydrogel was characterized by IR, XRD, TGA, SEM and AFM. The outcomes demonstrate that silver nanoparticles with uniform sizes were homogenously distributed through DAA/Ge hydrogel.
View Article and Find Full Text PDFIn addition to their lower cost and more environmentally friendly nature, cellulose nanofibers isolated from unbleached pulps offer different surface properties and functionality than those isolated from bleached pulps. At the same time, nanofibers isolated from unbleached pulps keep interesting properties such as hydrophilicity and mechanical strength, close to those isolated from bleached pulps. In the current work, rice straw nanofibers (RSNF) isolated from unbleached neutral sulfite pulp (lignin content 14%) were used with polysulfone (PSF) polymer to make membrane via phase inversion.
View Article and Find Full Text PDF2,3,6‑Tricarboxy cellulose nanofiber (TPC-CNFs) was prepared by 2,2,6,6-tetramethylpiperidine‑1‑oxyl (TEMPO) oxidation of dissolving cellulose pulp (selective at C-6) followed by periodate-chlorite oxidation (selective on C-2 and C-3). Characterization of the prepared samples were carried out using, atomic force microscope (AFM), carboxylate content determination, FTIR spectroscopy, X-ray diffraction and light transmittance spectra. Also, the mechanical properties of TEMPO-oxidized of cellulose nanofiber (T-CNFs) and TPC-CNFs with and without polyamide-amine-epichlorohydrin crosslinker (PAE) films were determined which the tensile strength were 8.
View Article and Find Full Text PDFBionanocomposites were developed by casting/evaporation of wheat gluten (WG), cellulose nanocrystals (CNC), and TiO2 nanoparticles. The effect of addition of different percentages of CNC, and TiO2 on tensile strength (TS), Young's modulus and water sensitivity was studied. A significant improvement in the studied properties is observed when 7.
View Article and Find Full Text PDFMultiphase hybrid materials were synthesized using carboxymethyl cellulose (CMC) as bioactive polymer, silica gel as matrix assisted networks and calcium phosphate as inorganic mineral phase. These hybrids were investigated with infrared spectroscopy, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and transmission electron microscopy. Biomimetic crystal growth nucleated from the CMC/silica hybrids was suggested as amorphous calcium phosphate with an evidence that hydroxyapatite, the mineralized component of bone, may be formed at high CMC content.
View Article and Find Full Text PDFPlant proteins are used - for the first time - in this work as bulk binders for cellulosic fibers in paper composites. Soy bean protein and wheat gluten were denatured by two methods, namely by: urea+NaOH and by urea+NaOH+acrylamide. Addition of increased amounts of the denatured proteins resulted in a significant increase in all paper strength properties.
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