This work deals with the relation between microstructure and electrochemical behavior of four iron-based FeCoC ternary alloys. First, the arc-melted studied alloys were characterized using differential thermal analyses and scanning electron microscopy. The established solidification sequences of these alloys show the presence of two primary crystallization phases (δ(Fe) and graphite) as well as two univariante lines : peritectic L + δ(Fe)↔γ(Fe) and eutectic L↔γ(Fe) + C(graphite).
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