Application of Taguchi method, response surface methodology, DFT calculation and molecular dynamics simulation into the removal of orange G and crystal violet by treated biomass.

In this work, the efficiency of the treated plant (TPCE) as an effective biosorbent for removing the orange G (OG) and crystal violet (CV) dyes from aqueous solution was investigated. TPCE was characterized by FT-IR, S, pH and SEM-EDX. The influence of parameters such as bioadsorbent dose, contact time, initial concentration, temperature and pH was tested using Taguchi experimental design (TED) with L orthogonal array (five parameters in two levels).

A Combined Experimental and Computational (DFT, RDF, MC and MD) Investigation of Epoxy Resin as a Potential Corrosion Inhibitor for Mild Steel in a 0.5 M HSO Environment.

In this work, a tetrafunctional epoxy resin entitled 2,3,4,5-tetraglycidyloxy pentanal (TGP) was tested and investigated as a potential corrosion inhibitor for mild steel (MS) in 0.5 M HSO solution. The corrosion inhibition process for mild steel was employed alongside various techniques, such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), temperature effect (TE), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and theoretical approaches (DFT, MC, RDF and MD).

Synthesis Characterization and Highly Protective Efficiency of Tetraglycidyloxy Pentanal Epoxy Prepolymer as a Potential Corrosion Inhibitor for Mild Steel in 1 M HCl Medium.

Anticorrosive protection efficiency of novel tetrafunctional epoxy prepolymer, namely 2,3,4,5-tetraglycidyloxy pentanal (TGP), for mild steel in 1 M HCl medium was assessed through potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), contact angle (CA), adsorption isotherm model, temperature effect and thermodynamic parameters. The synthesized TGP was characterized and confirmed by Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR). The inhibitory efficiencies found at lower concentration of the prepolymer TGP were85% (PDP) and 87.

Rheological properties of composite polymers and hybrid nanocomposites.

This paper summarizes a review of the viscosimetric, viscoelastic and rheological properties of polymers and hybrid nanocomposite polymers. Hybrid nanocomposites can be combined from natural fibers or synthetic fibers and/or both. The hybrid nanocomposite polymer offers the designer the opportunity to achieve the required characteristics to a considerable extent controlled by the choice of appropriate fibers or fillers and the polymer architecture.

Development and potential performance of prepolymer in corrosion inhibition for carbon steel in 1.0 M HCl: Outlooks from experimental and computational investigations.

Diglycidyl amino benzene (DGAB) epoxy prepolymer was investigated using Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy. Then, we highlighted the usefulness of DGAB epoxy prepolymer to improve the resistance of carbon steel (CS) in hydrochloric acid (1.0 M HCl) using weight loss (WL), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), scanning electron microscope (SEM), atomic force microscopy (AFM), density functional theory (DFT) and complexation calculations, molecular dynamics (MD) and meansquaredisplacement (MSD) simulations.

Evaluation of Mechanical compressive strength of cementitious matrix with 12% of IER formulated by modified polymer (NEPS) at different percentages.

During this paper, we improved the compressive strength of cementitious matrix based on ion exchanging resin (IER) at 12% and formulated by the modified novolac epoxy polymer surfactant (NEPS) at various percentages (0, 1, 2, 3, 4 and 5%). The results show that the introduction of 1% and 2% of NEPS in the cementitious matrix with 12% of IER increases the compressive strength compared to that of the basic matrix (from 7 to 90 days). However, the formulations 3, 4 and 5% show the compressive strength is less than that of the basic matrix (from 28 to 90 days).

Development rheological and anti-corrosion property of epoxy polymer and its composite.

Epoxy polymer, namely, decaglycidyl pentamethylene dianiline of phosphorus (DGPMDAP) was synthesized in three steps. The synthesis of epoxy polymer DGPMDAP was investigated by nuclear magnetic resonance spectroscopy, rheological analysis, scanning electron microscope (SEM), stationary and transient electrochemical methods (PDP and EIS), respectively. The rheological properties of composite (DGPMDAP/MDA/TiO) without and with different percentages of titanium dioxide (0%, 5%, 10% and 15%) increase with both the increase in frequency and with rate of load of titanium dioxide.

Textile finishing dyes and their impact on aquatic environs.

In the present review, we have been able to describe the different families of dyes and pigments used in textile finishing processes (Yarns, fabrics, nonwovens, knits and rugs) such as dyeing and printing. These dyes are reactive, direct, dispersed, indigo, sulphur and vats. Such that their presence in the liquid effluents resulting from the textile washing constitutes a serious risk, in the absence of their purification, for the quality of receiving aquatic environments.

Epoxy pre-polymers as new and effective materials for corrosion inhibition of carbon steel in acidic medium: Computational and experimental studies.

Present study is designed for the synthesis, characterization and corrosion inhibition behavior of two diamine aromatic epoxy pre-polymers (DAEPs) namely, N,N,N,N-tetrakis (oxiran-2-ylmethyl) benzene-1,2-diamine (DAEP1) and 4-methyl-N,N,N,N-tetrakis (oxiran-2-ylmethyl) benzene-1,2-diamine (DAEP2) for carbon steel corrosion in acidic medium. Synthesized DAEPs were characterized using spectral (Nuclear magnetic resonance (H NMR) and Fourier transform infrared-attenuated total reflection (FTIR-ATR)) techniques. Viscosity studies carried out at four different temperatures (20-80 °C) increase in temperature causes significant reduction in their viscosities.