In situ infrared aerosol spectroscopy for a variety of nerve agent simulants using flow-through photoacoustics.

We present newly measured results of an ongoing experimental program established to measure optical cross sections in the mid- and long-wave infrared for a variety of chemically and biologically based aerosols. For this study we consider only chemically derived aerosols, and in particular, a group of chemical compounds often used as simulants for the detection of extremely toxic organophosphorus nerve agents. These materials include: diethyl methylphosphonate (DEMP), dimethyl methylphosphonate (DMMP), diisopropyl methylphosphonate (DIMP), and diethyl phthalate (DEP).

Effect of surface roughness and complex indices of refraction on polarized thermal emission.

We present a series of measurements characterizing the dependence of polarized thermal emission on surface roughness. In particular, we measure the spectrally resolved degree of linear polarization (DOLP) for a series of roughened borosilicate (Pyrex) glass substrates as a function of the roughness parameter Ra, the root-mean-square slope distribution, and observation angle theta. Also measured are a series of smooth glass substrates coated with two particular polymers of interest, i.

In situ measurement of the infrared absorption and extinction of chemical and biologically derived aerosols using flow-through photoacoustics.

In an effort to establish a more reliable set of optical cross sections for a variety of chemical and biological aerosol simulants, we have developed a flow-through photoacoustic system that is capable of measuring absolute, mass-normalized extinction and absorption cross sections. By employing a flow-through design we avoid issues associated with closed aerosol photoacoustic systems and improve sensitivity. Although the results shown here were obtained for the tunable CO2 laser waveband region, i.

Measured infrared optical cross sections for a variety of chemical and biological aerosol simulants.

We conducted a series of spectral extinction measurements on a variety of aerosolized chemical and biological simulants over the spectral range 3-13 microm using conventional Fourier-transform IR (FTIR) aerosol spectroscopy. Samples consist of both aerosolized particulates and atomized liquids. Materials considered include Bacillus subtilis endospores, lyophilized ovalbumin, polyethylene glycol, dimethicone (SF-96), and three common background materials: kaolin clay (hydrated aluminum silicate), Arizona road dust (primarily SiO2), and diesel soot.