The use of pesticides in agriculture to protect crops against pests and diseases generates environmental contamination. The atmospheric compartment contributes to their dispersion at different distances from the application areas and to the exposure of organisms in untreated areas through dry and wet deposition. A multiresidue analytical method using the same TD-GC-MS analytical pipeline to quantify pesticide concentrations in both the atmosphere and rainwater was developed and tested in natura.
View Article and Find Full Text PDFA multiresidue method has been developed to analyze atrazine (ATZ), diuron (DIU), and their major degradation products, desethylatrazine (DEA), desisopropylatrazine (DIA), and dichlorophenylmethylurea in sewage sludge. Liquid chromatography coupled to electrospray tandem mass spectrometry (LC-ESI-MS-MS) allowed, in the multiple-reaction monitoring mode, the simultaneous analysis of these pesticides in only one run after their extraction with ethyl acetate-dichloromethane 90:10 (v/v) and a cleanup on a Florisil column. Stable isotopically labeled ATZ and DIU were used as internal standards to overcome matrix effects during the pesticide quantification.
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